Electric Field Mediated Ion Transport Through Charged Mesoporous Membranes

R. Schmuhl; W.B.S. de Lint; Klaas Keizer; Albert van den Berg; Johan E. ten Elshof

Electric Field Mediated Ion Transport Through Charged Mesoporous Membranes

R. Schmuhl, W.B.S. de Lint, Klaas Keizer, Albert van den Berg, Johan E. ten Elshof

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

Abstract

The transport of ions from aqueous solutions through a stacked Au/alpha-alumina/gamma-alumina/Au membrane under the influence of a dc potential difference is reported. The membrane shows high cation permselectivity at ionic strengths of ~1 mM at pH 4.3-6.5, which is associated with a combination of anion adsorption and double-layer overlap inside the pores of the gamma-alumina layer. The cation flux can be controlled by ionic strength, dc potential difference and pH.

Original language	Undefined
Title of host publication	Materials Research Society Symposium Proceedings
Editors	Vasilis N. Burganos, Richard D. Noble, Masashi Asaeda, Andre Ayral, Johann D. LeRoux
Place of Publication	Pittsburg, USA
Publisher	Materials Research Society
Pages	AA9.3.1-AA9.3.6
Number of pages	6
ISBN (Print)	9781558996892
Publication status	Published - 2003
Event	International Symposium on Membranes - Synthesis, Properties and Applications - Boston, Massachusetts, USA Duration: 2 Dec 2002 → 5 Dec 2002

Publication series

Name
Publisher	Materials Research Society
Volume	752
ISSN (Print)	0272-9172

Conference

Conference	International Symposium on Membranes - Synthesis, Properties and Applications
Period	2/12/02 → 5/12/02
Other	December 2-5, 2002

Keywords

IR-40809
METIS-214854

Cite this

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title = "Electric Field Mediated Ion Transport Through Charged Mesoporous Membranes",

abstract = "The transport of ions from aqueous solutions through a stacked Au/alpha-alumina/gamma-alumina/Au membrane under the influence of a dc potential difference is reported. The membrane shows high cation permselectivity at ionic strengths of ~1 mM at pH 4.3-6.5, which is associated with a combination of anion adsorption and double-layer overlap inside the pores of the gamma-alumina layer. The cation flux can be controlled by ionic strength, dc potential difference and pH.",

keywords = "IR-40809, METIS-214854",

author = "R. Schmuhl and {de Lint}, W.B.S. and Klaas Keizer and {van den Berg}, Albert and {ten Elshof}, {Johan E.}",

note = "MRS Proceedings 752 ; International Symposium on Membranes - Synthesis, Properties and Applications ; Conference date: 02-12-2002 Through 05-12-2002",

year = "2003",

language = "Undefined",

isbn = "9781558996892",

publisher = "Materials Research Society",

pages = "AA9.3.1--AA9.3.6",

editor = "Burganos, {Vasilis N.} and Noble, {Richard D.} and Masashi Asaeda and Andre Ayral and LeRoux, {Johann D.}",

booktitle = "Materials Research Society Symposium Proceedings",

address = "United States",

}

Schmuhl, R, de Lint, WBS, Keizer, K, van den Berg, A & ten Elshof, JE 2003, Electric Field Mediated Ion Transport Through Charged Mesoporous Membranes. in VN Burganos, RD Noble, M Asaeda, A Ayral & JD LeRoux (eds), Materials Research Society Symposium Proceedings. Materials Research Society, Pittsburg, USA, pp. AA9.3.1-AA9.3.6, International Symposium on Membranes - Synthesis, Properties and Applications, 2/12/02.

Electric Field Mediated Ion Transport Through Charged Mesoporous Membranes. / Schmuhl, R.; de Lint, W.B.S.; Keizer, Klaas et al.
Materials Research Society Symposium Proceedings. ed. / Vasilis N. Burganos; Richard D. Noble; Masashi Asaeda; Andre Ayral; Johann D. LeRoux. Pittsburg, USA: Materials Research Society, 2003. p. AA9.3.1-AA9.3.6.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

TY - GEN

T1 - Electric Field Mediated Ion Transport Through Charged Mesoporous Membranes

AU - Schmuhl, R.

AU - de Lint, W.B.S.

AU - Keizer, Klaas

AU - van den Berg, Albert

AU - ten Elshof, Johan E.

N1 - MRS Proceedings 752

PY - 2003

Y1 - 2003

N2 - The transport of ions from aqueous solutions through a stacked Au/alpha-alumina/gamma-alumina/Au membrane under the influence of a dc potential difference is reported. The membrane shows high cation permselectivity at ionic strengths of ~1 mM at pH 4.3-6.5, which is associated with a combination of anion adsorption and double-layer overlap inside the pores of the gamma-alumina layer. The cation flux can be controlled by ionic strength, dc potential difference and pH.

AB - The transport of ions from aqueous solutions through a stacked Au/alpha-alumina/gamma-alumina/Au membrane under the influence of a dc potential difference is reported. The membrane shows high cation permselectivity at ionic strengths of ~1 mM at pH 4.3-6.5, which is associated with a combination of anion adsorption and double-layer overlap inside the pores of the gamma-alumina layer. The cation flux can be controlled by ionic strength, dc potential difference and pH.

KW - IR-40809

KW - METIS-214854

M3 - Conference contribution

SN - 9781558996892

SP - AA9.3.1-AA9.3.6

BT - Materials Research Society Symposium Proceedings

A2 - Burganos, Vasilis N.

A2 - Noble, Richard D.

A2 - Asaeda, Masashi

A2 - Ayral, Andre

A2 - LeRoux, Johann D.

PB - Materials Research Society

CY - Pittsburg, USA

T2 - International Symposium on Membranes - Synthesis, Properties and Applications

Y2 - 2 December 2002 through 5 December 2002

ER -