TY - JOUR
T1 - Electrical and catalytic properties of some oxides with the fluorite or pyrochlore structure. CO oxidation on some compounds derived from Gd2Zr2O7
AU - Korf, Stefan J.
AU - Koopmans, Harry J.A.
AU - Lippens Jr., Bernard C.
AU - Burggraaf, Anthonie J.
AU - Gellings, Paul J.
PY - 1987/12/1
Y1 - 1987/12/1
N2 - The catalytic properties of some mixed zirconates with the pyrochlore or fluorite structure have been investigated using CO oxidation as the test reaction. The presence of terbium ions, leading to mixed conductivity, and the extent of pyrochlore ordering affect the kinetic behaviour and the catalytic activity of the investigated materials. Bismuth-containing compounds show an increased rate of reoxidation.
AB - The catalytic properties of some mixed zirconates with the pyrochlore or fluorite structure have been investigated using CO oxidation as the test reaction. The presence of terbium ions, leading to mixed conductivity, and the extent of pyrochlore ordering affect the kinetic behaviour and the catalytic activity of the investigated materials. Bismuth-containing compounds show an increased rate of reoxidation.
UR - http://www.scopus.com/inward/record.url?scp=37049071514&partnerID=8YFLogxK
U2 - 10.1039/F19878301485
DO - 10.1039/F19878301485
M3 - Article
AN - SCOPUS:37049071514
SN - 0300-9599
VL - 83
SP - 1485
EP - 1491
JO - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
JF - Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases
IS - 5
ER -