Electronic properties of individual diarylethene molecules studies using scanning tunneling spectroscopy

  • T.C. Pijper
  • , Tibor Kudernac
  • , Nathalie Hélène Katsonis
  • , M. van der Maas
  • , B.L. Feringa
  • , B. van Wees

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Abstract

The investigation of the electronic conduction through monosulfurdiarylethene (1S-DE) immobilized in an insulating dodecanethiol matrix on a goldsurface was addressed. Scanning tunnelingspectroscopy allows to probe spatially the frontier molecular orbitals of 1S-DE at 77 K. We locally extracted the electronic highest occupied molecular orbital-lowest unoccupied molecular orbital gap of 1S-DE with the value of 1.56 eV. This attempt reveals the importance of scanning tunnelingspectroscopy as a tool to measure the charge transport properties of diarylethene towards the realization of a switching-based molecular device.
Original languageUndefined
Article number083716
Pages (from-to)83716-1-083716-6
Number of pages6
JournalJournal of Applied Physics
Volume111
Issue number8
DOIs
Publication statusPublished - 2012

Keywords

  • IR-85015
  • METIS-293502

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