TY - JOUR
T1 - Encapsulation of Ammonium Polyphosphate in Lignin Nanocontainers Enhances Dispersion and Flame Retardancy in Polylactic Acid Foams
AU - Peil, Stefan
AU - Mouhoubi, Rakine
AU - Streekstra, Ruben
AU - Ridard, Hugo
AU - Veith, Lothar
AU - Ali, Wael
AU - Mayer-Gall, Thomas
AU - Duvigneau, Joost
AU - Wurm, Frederik R.
N1 - Publisher Copyright:
© 2024 The Authors. Published by American Chemical Society
PY - 2024/5/8
Y1 - 2024/5/8
N2 - Ammonium polyphosphate (APP) holds significant potential as a nonhalogenated flame retardant. However, achieving compatibility between polar APP and nonpolar polymer matrices remains challenging. Here, we present a synergistic submicrometer-sized flame retardant system composed of hydrophilic APP encapsulated in lignosulfonate capsules. These lignin nanocontainers (LNCs) are prepared via interfacial cross-linking of lignosulfonate using toluene-2,4-diisocyanate (TDI) in inverse miniemulsion, which is stabilized by polyglycerin polyricinoleate (PGPR), a food additive. Excess isocyanate groups on the surface of the LNCs enable the surface-grafting with hydroxy-functionalized polymers, e.g., poly(lactic acid) (PLA), and enhance the dispersion of APP-loaded LNCs in the PLA matrix. Furthermore, APP-loaded LNCs act as heterogeneous nucleation agents in CO2 batch foaming. The incorporation of 5-20 wt % LNCs resulted in fine-celled foams, as evidenced by the reduced cell diameters (29 ± 17 μm compared to virgin PLA foams (63 ± 31 μm)) and increased cell density of LNC-loaded PLA foams compared to pristine PLA foams from 2 × 107 to 4 × 108 cells cm-3. Notably, the flame retardancy of the LNC-enriched PLA foams was significantly enhanced. The combined carbonization effect of lignin, PGPR, and APP led to an elevated foam char yield, increasing from 0.9 wt % (pristine PLA) to 7.3 wt % (20 wt % LNC-loaded PLA). The experimental limiting oxygen index (LOI) increased from 21% (pristine PLA foams) to 24.5% (20 wt % LNC-loaded PLA foams). UL-94 test proved a V0 rating with only 9 wt % of loaded LNCs. Microcone Calorimeter data further underlines the systematic trend of APP added to the foams with a decreased heat release rate, depending on the amount of FR. Together, our results underline the effectiveness of biobased and biodegradable polymers in lightweight packaging and construction applications with enhanced flame-retardancy.
AB - Ammonium polyphosphate (APP) holds significant potential as a nonhalogenated flame retardant. However, achieving compatibility between polar APP and nonpolar polymer matrices remains challenging. Here, we present a synergistic submicrometer-sized flame retardant system composed of hydrophilic APP encapsulated in lignosulfonate capsules. These lignin nanocontainers (LNCs) are prepared via interfacial cross-linking of lignosulfonate using toluene-2,4-diisocyanate (TDI) in inverse miniemulsion, which is stabilized by polyglycerin polyricinoleate (PGPR), a food additive. Excess isocyanate groups on the surface of the LNCs enable the surface-grafting with hydroxy-functionalized polymers, e.g., poly(lactic acid) (PLA), and enhance the dispersion of APP-loaded LNCs in the PLA matrix. Furthermore, APP-loaded LNCs act as heterogeneous nucleation agents in CO2 batch foaming. The incorporation of 5-20 wt % LNCs resulted in fine-celled foams, as evidenced by the reduced cell diameters (29 ± 17 μm compared to virgin PLA foams (63 ± 31 μm)) and increased cell density of LNC-loaded PLA foams compared to pristine PLA foams from 2 × 107 to 4 × 108 cells cm-3. Notably, the flame retardancy of the LNC-enriched PLA foams was significantly enhanced. The combined carbonization effect of lignin, PGPR, and APP led to an elevated foam char yield, increasing from 0.9 wt % (pristine PLA) to 7.3 wt % (20 wt % LNC-loaded PLA). The experimental limiting oxygen index (LOI) increased from 21% (pristine PLA foams) to 24.5% (20 wt % LNC-loaded PLA foams). UL-94 test proved a V0 rating with only 9 wt % of loaded LNCs. Microcone Calorimeter data further underlines the systematic trend of APP added to the foams with a decreased heat release rate, depending on the amount of FR. Together, our results underline the effectiveness of biobased and biodegradable polymers in lightweight packaging and construction applications with enhanced flame-retardancy.
KW - UT-Hybrid-D
KW - CO batch foaming
KW - Composite
KW - Halogen-free flame retardant
KW - Lignin
KW - Biobased
UR - http://www.scopus.com/inward/record.url?scp=85192827691&partnerID=8YFLogxK
U2 - 10.1021/acsapm.4c00787
DO - 10.1021/acsapm.4c00787
M3 - Article
AN - SCOPUS:85192827691
SN - 2637-6105
VL - 6
SP - 6096
EP - 6107
JO - ACS Applied Polymer Materials
JF - ACS Applied Polymer Materials
IS - 10
ER -