TY - JOUR
T1 - Engineering of Adhesion at Metal-Poly(lactic acid) Interfaces by Poly(dopamine)
T2 - The Effect of the Annealing Temperature
AU - Kafkopoulos, Georgios
AU - Karakurt, Ezgi
AU - Pinto Enes Martinho, Ricardo
AU - Duvigneau, Joost
AU - Vancso, G. Julius
N1 - Publisher Copyright:
© 2023 The Authors. Published by American Chemical Society.
PY - 2023/7/6
Y1 - 2023/7/6
N2 - Control over adhesion at interfaces from strong bonding to release between thermoplastic polymers (TPs) and metal oxides is highly significant for polymer composites. In this work, we showcase a simple and inexpensive method to tune adhesion between a TP of growing interest, poly(lactic acid) (PLA), and two commercial metal alloys, based on titanium and stainless steel. This is realized by coating titanium and stainless steel wires with polydopamine (PDA), thermally treating them under vacuum at temperatures ranging from 25 to 250 °C, and then comolding them with PLA to form pullout specimens for adhesion tests. Pullout results indicate that PDA coatings treated at low temperatures up to a given threshold significantly improve adhesion between PLA and the metals. Conversely, at higher PDA annealing temperatures beyond the threshold, interfacial bonding gradually declines. The excellent control over interfacial adhesion is attributed to the thermally induced transformation of PDA. In this work, we show using thermogravimetric analysis, X-ray photoelectron spectroscopy, Fourier transform infrared, and 13C solid-state NMR that the extent of the thermal transformation is dependent on the annealing temperature. By selecting the annealing temperature, we vary the concentration of primary amine and hydroxyl groups in PDA, which influences adhesion at the metal/PLA interface. We believe that these findings contribute to optimizing and broadening the applications of PDA in composite materials.
AB - Control over adhesion at interfaces from strong bonding to release between thermoplastic polymers (TPs) and metal oxides is highly significant for polymer composites. In this work, we showcase a simple and inexpensive method to tune adhesion between a TP of growing interest, poly(lactic acid) (PLA), and two commercial metal alloys, based on titanium and stainless steel. This is realized by coating titanium and stainless steel wires with polydopamine (PDA), thermally treating them under vacuum at temperatures ranging from 25 to 250 °C, and then comolding them with PLA to form pullout specimens for adhesion tests. Pullout results indicate that PDA coatings treated at low temperatures up to a given threshold significantly improve adhesion between PLA and the metals. Conversely, at higher PDA annealing temperatures beyond the threshold, interfacial bonding gradually declines. The excellent control over interfacial adhesion is attributed to the thermally induced transformation of PDA. In this work, we show using thermogravimetric analysis, X-ray photoelectron spectroscopy, Fourier transform infrared, and 13C solid-state NMR that the extent of the thermal transformation is dependent on the annealing temperature. By selecting the annealing temperature, we vary the concentration of primary amine and hydroxyl groups in PDA, which influences adhesion at the metal/PLA interface. We believe that these findings contribute to optimizing and broadening the applications of PDA in composite materials.
KW - interfacial adhesion
KW - PLA
KW - polydopamine
KW - polymer−metal bonding
KW - thermal treatment
KW - UT-Hybrid-D
UR - http://www.scopus.com/inward/record.url?scp=85164920290&partnerID=8YFLogxK
U2 - 10.1021/acsapm.3c00672
DO - 10.1021/acsapm.3c00672
M3 - Article
AN - SCOPUS:85164920290
SN - 2637-6105
VL - 5
SP - 5370
EP - 5380
JO - ACS Applied Polymer Materials
JF - ACS Applied Polymer Materials
IS - 7
ER -