Formation and Detection of Clay Network Structure in Poly(propylene)/Layered Silicate Nanocomposites

Ágnes Ábrányi; László Százdi; Béla Pukánszky Jr.; G. Julius Vancsó; Béla Pukánszky

doi:10.1002/marc.200500687

Formation and Detection of Clay Network Structure in Poly(propylene)/Layered Silicate Nanocomposites

Ágnes Ábrányi, László Százdi, Béla Pukánszky Jr., G. Julius Vancsó, Béla Pukánszky^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

55 Citations (Scopus)

6 Downloads (Pure)

Abstract

The study of the structure and the rheological properties of poly(propylene) (PP)/montmorillonite (MMT)/maleinated PP (MAPP) composites strongly suggests that a silicate network may form under certain conditions. Network formation could not be proven unambiguously with the usual techniques, i.e., with TEM and by plotting the frequency dependence of viscoelastic properties. Cole-Cole plots detect the network very sensitively. A certain number of silicate layers are needed to create a house-of-cards structure. A threshold concentration of MAPP exists in the investigated system, which depends on the silicate content.

Original language	English
Pages (from-to)	132-135
Number of pages	4
Journal	Macromolecular rapid communications
Volume	27
Issue number	2
DOIs	https://doi.org/10.1002/marc.200500687
Publication status	Published - 2006

Keywords

Fibers
Young's modulus
Electrospinning
Force-displacement curve
Orientation
n/a OA procedure

Access to Document

10.1002/marc.200500687

Cite this

@article{18ff4a0ba98647e1a7c81d013e7f9b12,

title = "Formation and Detection of Clay Network Structure in Poly(propylene)/Layered Silicate Nanocomposites",

abstract = "The study of the structure and the rheological properties of poly(propylene) (PP)/montmorillonite (MMT)/maleinated PP (MAPP) composites strongly suggests that a silicate network may form under certain conditions. Network formation could not be proven unambiguously with the usual techniques, i.e., with TEM and by plotting the frequency dependence of viscoelastic properties. Cole-Cole plots detect the network very sensitively. A certain number of silicate layers are needed to create a house-of-cards structure. A threshold concentration of MAPP exists in the investigated system, which depends on the silicate content.",

keywords = "Fibers, Young's modulus, Electrospinning, Force-displacement curve, Orientation, n/a OA procedure",

author = "{\'A}gnes {\'A}br{\'a}nyi and L{\'a}szl{\'o} Sz{\'a}zdi and {Puk{\'a}nszky Jr.}, B{\'e}la and Vancs{\'o}, {G. Julius} and B{\'e}la Puk{\'a}nszky",

year = "2006",

doi = "10.1002/marc.200500687",

language = "English",

volume = "27",

pages = "132--135",

journal = "Macromolecular rapid communications",

issn = "1022-1336",

publisher = "Wiley-VCH Verlag",

number = "2",

}

TY - JOUR

T1 - Formation and Detection of Clay Network Structure in Poly(propylene)/Layered Silicate Nanocomposites

AU - Ábrányi, Ágnes

AU - Százdi, László

AU - Pukánszky Jr., Béla

AU - Vancsó, G. Julius

AU - Pukánszky, Béla

PY - 2006

Y1 - 2006

N2 - The study of the structure and the rheological properties of poly(propylene) (PP)/montmorillonite (MMT)/maleinated PP (MAPP) composites strongly suggests that a silicate network may form under certain conditions. Network formation could not be proven unambiguously with the usual techniques, i.e., with TEM and by plotting the frequency dependence of viscoelastic properties. Cole-Cole plots detect the network very sensitively. A certain number of silicate layers are needed to create a house-of-cards structure. A threshold concentration of MAPP exists in the investigated system, which depends on the silicate content.

AB - The study of the structure and the rheological properties of poly(propylene) (PP)/montmorillonite (MMT)/maleinated PP (MAPP) composites strongly suggests that a silicate network may form under certain conditions. Network formation could not be proven unambiguously with the usual techniques, i.e., with TEM and by plotting the frequency dependence of viscoelastic properties. Cole-Cole plots detect the network very sensitively. A certain number of silicate layers are needed to create a house-of-cards structure. A threshold concentration of MAPP exists in the investigated system, which depends on the silicate content.

KW - Fibers

KW - Young's modulus

KW - Electrospinning

KW - Force-displacement curve

KW - Orientation

KW - n/a OA procedure

U2 - 10.1002/marc.200500687

DO - 10.1002/marc.200500687

M3 - Article

SN - 1022-1336

VL - 27

SP - 132

EP - 135

JO - Macromolecular rapid communications

JF - Macromolecular rapid communications

IS - 2

ER -

Formation and Detection of Clay Network Structure in Poly(propylene)/Layered Silicate Nanocomposites

Abstract

Keywords

Access to Document

Fingerprint

Cite this