Functionalized 1 '-Substituted Iodoferrocenes and Their Pd-Catalyzed Heck Cross-Coupling Reactions

Max Roemer, Bruno Donnadieu, Christian A. Nijhuis*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

6 Citations (Scopus)

Abstract

This paper describes the preparation of a variety of 1′‐substituted iodoferrocenes from 1‐iodo‐1′‐(tri‐n‐butyltin)ferrocene by an electrophilic substitution of the tri‐n‐butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.
Original languageEnglish
Pages (from-to)1314-1318
JournalEuropean journal of inorganic chemistry
Volume2016
Issue number9
DOIs
Publication statusPublished - Mar 2016
Externally publishedYes

Keywords

  • Iodoferrocenes
  • Bridged ferrocenes
  • Cross-coupling
  • Homogeneous catalysis
  • Acylation

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