Abstract
This paper describes the preparation of a variety of 1′‐substituted iodoferrocenes from 1‐iodo‐1′‐(tri‐n‐butyltin)ferrocene by an electrophilic substitution of the tri‐n‐butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.
Original language | English |
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Pages (from-to) | 1314-1318 |
Journal | European journal of inorganic chemistry |
Volume | 2016 |
Issue number | 9 |
DOIs | |
Publication status | Published - Mar 2016 |
Externally published | Yes |
Keywords
- Iodoferrocenes
- Bridged ferrocenes
- Cross-coupling
- Homogeneous catalysis
- Acylation