Functionalized 1 '-Substituted Iodoferrocenes and Their Pd-Catalyzed Heck Cross-Coupling Reactions

Max Roemer; Bruno Donnadieu; Christian A. Nijhuis

doi:10.1002/ejic.201501451

Functionalized 1 '-Substituted Iodoferrocenes and Their Pd-Catalyzed Heck Cross-Coupling Reactions

Max Roemer
, Bruno Donnadieu
, Christian A. Nijhuis^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

13 Citations (Scopus)

Abstract

This paper describes the preparation of a variety of 1′‐substituted iodoferrocenes from 1‐iodo‐1′‐(tri‐n‐butyltin)ferrocene by an electrophilic substitution of the tri‐n‐butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.

Original language	English
Pages (from-to)	1314-1318
Journal	European journal of inorganic chemistry
Volume	2016
Issue number	9
DOIs	https://doi.org/10.1002/ejic.201501451
Publication status	Published - Mar 2016
Externally published	Yes

Keywords

Iodoferrocenes
Bridged ferrocenes
Cross-coupling
Homogeneous catalysis
Acylation

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10.1002/ejic.201501451

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title = "Functionalized 1 '-Substituted Iodoferrocenes and Their Pd-Catalyzed Heck Cross-Coupling Reactions",

abstract = "This paper describes the preparation of a variety of 1′‐substituted iodoferrocenes from 1‐iodo‐1′‐(tri‐n‐butyltin)ferrocene by an electrophilic substitution of the tri‐n‐butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.",

keywords = "Iodoferrocenes, Bridged ferrocenes, Cross-coupling, Homogeneous catalysis, Acylation",

author = "Max Roemer and Bruno Donnadieu and Nijhuis, \{Christian A.\}",

year = "2016",

month = mar,

doi = "10.1002/ejic.201501451",

language = "English",

volume = "2016",

pages = "1314--1318",

journal = "European journal of inorganic chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Functionalized 1 '-Substituted Iodoferrocenes and Their Pd-Catalyzed Heck Cross-Coupling Reactions

AU - Roemer, Max

AU - Donnadieu, Bruno

AU - Nijhuis, Christian A.

PY - 2016/3

Y1 - 2016/3

N2 - This paper describes the preparation of a variety of 1′‐substituted iodoferrocenes from 1‐iodo‐1′‐(tri‐n‐butyltin)ferrocene by an electrophilic substitution of the tri‐n‐butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.

AB - This paper describes the preparation of a variety of 1′‐substituted iodoferrocenes from 1‐iodo‐1′‐(tri‐n‐butyltin)ferrocene by an electrophilic substitution of the tri‐n‐butyltin moiety with functionalized acylium and benzoylium species. Additionally, we demonstrate a Heck coupling protocol for these functionalized iodoferrocenes with ethenylferrocene.

KW - Iodoferrocenes

KW - Bridged ferrocenes

KW - Cross-coupling

KW - Homogeneous catalysis

KW - Acylation

U2 - 10.1002/ejic.201501451

DO - 10.1002/ejic.201501451

M3 - Article

SN - 1434-1948

VL - 2016

SP - 1314

EP - 1318

JO - European journal of inorganic chemistry

JF - European journal of inorganic chemistry

IS - 9

ER -

Functionalized 1 '-Substituted Iodoferrocenes and Their Pd-Catalyzed Heck Cross-Coupling Reactions

Abstract

Keywords

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