Gas phase hydroformylation of ethylene using organometalic Rh-complexes as heterogeneous catalysts

V.I. Zapirtan; Barbara Mojet; J.G. van Ommen; J. Spitzer; Leonardus Lefferts

doi:10.1007/s10562-004-3747-8

Gas phase hydroformylation of ethylene using organometalic Rh-complexes as heterogeneous catalysts

V.I. Zapirtan
, Barbara Mojet
, J.G. van Ommen
, J. Spitzer
, Leonardus Lefferts

Research output: Contribution to journal › Article › Academic › peer-review

21 Citations (Scopus)

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Abstract

The heterogeneously catalysed gas phase hydroformylation of ethylene to propionaldehyde was studied over solid RhCl(PPh3)3 and RhCl(CO)(PPh3)2. At 3 bar and 185 °C, an active phase formed from RhCl(PPh3)3 which was different from RhCl(CO)(PPh3)2 under the reaction conditions studied. The selectivity of RhCl(PPh3)3 to propanal was much better than that of supported Rh-metal. Thus, solid metal-complexes operated in gas phase reactions clearly hold promise as a new class of heterogeneous catalysts.

Original language	English
Pages (from-to)	43-47
Number of pages	5
Journal	Catalysis letters
Volume	101
Issue number	1-2
DOIs	https://doi.org/10.1007/s10562-004-3747-8
Publication status	Published - 2005

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title = "Gas phase hydroformylation of ethylene using organometalic Rh-complexes as heterogeneous catalysts",

abstract = "The heterogeneously catalysed gas phase hydroformylation of ethylene to propionaldehyde was studied over solid RhCl(PPh3)3 and RhCl(CO)(PPh3)2. At 3 bar and 185 °C, an active phase formed from RhCl(PPh3)3 which was different from RhCl(CO)(PPh3)2 under the reaction conditions studied. The selectivity of RhCl(PPh3)3 to propanal was much better than that of supported Rh-metal. Thus, solid metal-complexes operated in gas phase reactions clearly hold promise as a new class of heterogeneous catalysts.",

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T1 - Gas phase hydroformylation of ethylene using organometalic Rh-complexes as heterogeneous catalysts

AU - Zapirtan, V.I.

AU - Mojet, Barbara

AU - van Ommen, J.G.

AU - Spitzer, J.

AU - Lefferts, Leonardus

PY - 2005

Y1 - 2005

N2 - The heterogeneously catalysed gas phase hydroformylation of ethylene to propionaldehyde was studied over solid RhCl(PPh3)3 and RhCl(CO)(PPh3)2. At 3 bar and 185 °C, an active phase formed from RhCl(PPh3)3 which was different from RhCl(CO)(PPh3)2 under the reaction conditions studied. The selectivity of RhCl(PPh3)3 to propanal was much better than that of supported Rh-metal. Thus, solid metal-complexes operated in gas phase reactions clearly hold promise as a new class of heterogeneous catalysts.

AB - The heterogeneously catalysed gas phase hydroformylation of ethylene to propionaldehyde was studied over solid RhCl(PPh3)3 and RhCl(CO)(PPh3)2. At 3 bar and 185 °C, an active phase formed from RhCl(PPh3)3 which was different from RhCl(CO)(PPh3)2 under the reaction conditions studied. The selectivity of RhCl(PPh3)3 to propanal was much better than that of supported Rh-metal. Thus, solid metal-complexes operated in gas phase reactions clearly hold promise as a new class of heterogeneous catalysts.

U2 - 10.1007/s10562-004-3747-8

DO - 10.1007/s10562-004-3747-8

M3 - Article

SN - 1011-372X

VL - 101

SP - 43

EP - 47

JO - Catalysis letters

JF - Catalysis letters

IS - 1-2

ER -

Gas phase hydroformylation of ethylene using organometalic Rh-complexes as heterogeneous catalysts

Abstract

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