Gas-to-liquids process using multi-phase flow, non-thermal plasma microreactor

Anıl Agiral; Tomohiro Nozaki; Masahiko Nakase; Shuhei Yuzawa; Ken Okazaki; J.G.E. Han) Gardeniers

doi:10.1016/j.cej.2010.10.050

Gas-to-liquids process using multi-phase flow, non-thermal plasma microreactor

Anıl Agiral, Tomohiro Nozaki, Masahiko Nakase, Shuhei Yuzawa, Ken Okazaki, J.G.E. Han) Gardeniers

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Abstract

A multi-phase flow non-thermal plasma microreactor based on dielectric barrier discharge has been developed for partial oxidation of methane to liquid oxygenates at atmospheric pressure. A pulsed water injection method has been used to remove condensable liquid components from the active discharge region. The effect of the pulsed water injection on methane conversion, yield of oxygenates and hydrogen peroxide (H2O2) formation as an intermediate oxidation product is discussed. H2O2 has been found to oxidize formaldehyde in the post-discharge liquid. The overall kinetics of the gas-to-liquids process is described by dividing process into three different stages: electron impact dissociation of methane and oxygen and radical reactions in the gas phase followed by condensation of oxygenates and oxidation in the post-discharge liquid

Original language	English
Pages (from-to)	560-566
Number of pages	7
Journal	Chemical Engineering Journal
Volume	167
Issue number	2-3
DOIs	https://doi.org/10.1016/j.cej.2010.10.050
Publication status	Published - 2011

Keywords

METIS-274589
IR-94145

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10.1016/j.cej.2010.10.050

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title = "Gas-to-liquids process using multi-phase flow, non-thermal plasma microreactor",

abstract = "A multi-phase flow non-thermal plasma microreactor based on dielectric barrier discharge has been developed for partial oxidation of methane to liquid oxygenates at atmospheric pressure. A pulsed water injection method has been used to remove condensable liquid components from the active discharge region. The effect of the pulsed water injection on methane conversion, yield of oxygenates and hydrogen peroxide (H2O2) formation as an intermediate oxidation product is discussed. H2O2 has been found to oxidize formaldehyde in the post-discharge liquid. The overall kinetics of the gas-to-liquids process is described by dividing process into three different stages: electron impact dissociation of methane and oxygen and radical reactions in the gas phase followed by condensation of oxygenates and oxidation in the post-discharge liquid",

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author = "Anıl Agiral and Tomohiro Nozaki and Masahiko Nakase and Shuhei Yuzawa and Ken Okazaki and Gardeniers, {J.G.E. Han)}",

note = "Special Issue - IMRET 11: 11th International Conference on Microreaction Technology ",

year = "2011",

doi = "10.1016/j.cej.2010.10.050",

language = "English",

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T1 - Gas-to-liquids process using multi-phase flow, non-thermal plasma microreactor

AU - Agiral, Anıl

AU - Nozaki, Tomohiro

AU - Nakase, Masahiko

AU - Yuzawa, Shuhei

AU - Okazaki, Ken

AU - Gardeniers, J.G.E. Han)

N1 - Special Issue - IMRET 11: 11th International Conference on Microreaction Technology

PY - 2011

Y1 - 2011

N2 - A multi-phase flow non-thermal plasma microreactor based on dielectric barrier discharge has been developed for partial oxidation of methane to liquid oxygenates at atmospheric pressure. A pulsed water injection method has been used to remove condensable liquid components from the active discharge region. The effect of the pulsed water injection on methane conversion, yield of oxygenates and hydrogen peroxide (H2O2) formation as an intermediate oxidation product is discussed. H2O2 has been found to oxidize formaldehyde in the post-discharge liquid. The overall kinetics of the gas-to-liquids process is described by dividing process into three different stages: electron impact dissociation of methane and oxygen and radical reactions in the gas phase followed by condensation of oxygenates and oxidation in the post-discharge liquid

AB - A multi-phase flow non-thermal plasma microreactor based on dielectric barrier discharge has been developed for partial oxidation of methane to liquid oxygenates at atmospheric pressure. A pulsed water injection method has been used to remove condensable liquid components from the active discharge region. The effect of the pulsed water injection on methane conversion, yield of oxygenates and hydrogen peroxide (H2O2) formation as an intermediate oxidation product is discussed. H2O2 has been found to oxidize formaldehyde in the post-discharge liquid. The overall kinetics of the gas-to-liquids process is described by dividing process into three different stages: electron impact dissociation of methane and oxygen and radical reactions in the gas phase followed by condensation of oxygenates and oxidation in the post-discharge liquid

KW - METIS-274589

KW - IR-94145

U2 - 10.1016/j.cej.2010.10.050

DO - 10.1016/j.cej.2010.10.050

M3 - Article

SN - 1385-8947

VL - 167

SP - 560

EP - 566

JO - Chemical Engineering Journal

JF - Chemical Engineering Journal

IS - 2-3

ER -

Gas-to-liquids process using multi-phase flow, non-thermal plasma microreactor

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Keywords

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