Gas transport and separation with ceramic membranes. Part II: Synthesis and separation properties of microporous membranes

R.J.R. Uhlhorn, R.J.R. Uhlhorn, Klaas Keizer, Anthonie Burggraaf, A.J. Burggraaf

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Abstract

Non-supported microporous silica (amorphous) and titania thin films were made by the polymeric gel route. The titania system consisted of particles smaller than 5 nm. Reproducible modification of supported γ-alumina films with silica demands a strict control of every modification step. Silica films of 30–60 nm thickness on top of and presumably partly inside the γ-alumina film were realised. The permeabilities of helium and hydrogen through this film are activated, while the propylene permeability was below the detection limit. Separation factors of a H2---C3H6 mixture are larger than 200 at 200 °C with a flux of the preferentially hydrogen of 1.6 × 10−6 mol/m2-sec-Pa. The pores must be of molecular dimensions to realise this (< 1 nm diameter). Preliminary research shows that changes in the synthesis parameters result in higher activation energies and improved separation properties. The relation between synthesis, resulting microstructure and gas separation properties, however, is not yet fully understood.
Original languageUndefined
Pages (from-to)271-287
Number of pages16
JournalJournal of membrane science
Volume0
Issue number66
DOIs
Publication statusPublished - 1992

Keywords

  • METIS-106817
  • IR-12636

Cite this

Uhlhorn, R.J.R. ; Uhlhorn, R.J.R. ; Keizer, Klaas ; Burggraaf, Anthonie ; Burggraaf, A.J. / Gas transport and separation with ceramic membranes. Part II: Synthesis and separation properties of microporous membranes. In: Journal of membrane science. 1992 ; Vol. 0, No. 66. pp. 271-287.
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Gas transport and separation with ceramic membranes. Part II: Synthesis and separation properties of microporous membranes. / Uhlhorn, R.J.R.; Uhlhorn, R.J.R.; Keizer, Klaas; Burggraaf, Anthonie; Burggraaf, A.J.

In: Journal of membrane science, Vol. 0, No. 66, 1992, p. 271-287.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Gas transport and separation with ceramic membranes. Part II: Synthesis and separation properties of microporous membranes

AU - Uhlhorn, R.J.R.

AU - Uhlhorn, R.J.R.

AU - Keizer, Klaas

AU - Burggraaf, Anthonie

AU - Burggraaf, A.J.

PY - 1992

Y1 - 1992

N2 - Non-supported microporous silica (amorphous) and titania thin films were made by the polymeric gel route. The titania system consisted of particles smaller than 5 nm. Reproducible modification of supported γ-alumina films with silica demands a strict control of every modification step. Silica films of 30–60 nm thickness on top of and presumably partly inside the γ-alumina film were realised. The permeabilities of helium and hydrogen through this film are activated, while the propylene permeability was below the detection limit. Separation factors of a H2---C3H6 mixture are larger than 200 at 200 °C with a flux of the preferentially hydrogen of 1.6 × 10−6 mol/m2-sec-Pa. The pores must be of molecular dimensions to realise this (< 1 nm diameter). Preliminary research shows that changes in the synthesis parameters result in higher activation energies and improved separation properties. The relation between synthesis, resulting microstructure and gas separation properties, however, is not yet fully understood.

AB - Non-supported microporous silica (amorphous) and titania thin films were made by the polymeric gel route. The titania system consisted of particles smaller than 5 nm. Reproducible modification of supported γ-alumina films with silica demands a strict control of every modification step. Silica films of 30–60 nm thickness on top of and presumably partly inside the γ-alumina film were realised. The permeabilities of helium and hydrogen through this film are activated, while the propylene permeability was below the detection limit. Separation factors of a H2---C3H6 mixture are larger than 200 at 200 °C with a flux of the preferentially hydrogen of 1.6 × 10−6 mol/m2-sec-Pa. The pores must be of molecular dimensions to realise this (< 1 nm diameter). Preliminary research shows that changes in the synthesis parameters result in higher activation energies and improved separation properties. The relation between synthesis, resulting microstructure and gas separation properties, however, is not yet fully understood.

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