Germanium/MoS2: Competition between the growth of germanene and intercalation

Z. Jiao, Q. Yao, A. N. Rudenko, L. Zhang*, H. J.W. Zandvliet*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

9 Citations (Scopus)
57 Downloads (Pure)


We have scrutinized the growth of germanium (Ge) on molybdenum disulfide (MoS2) using scanning tunneling microscopy and density functional theory calculations in order to resolve the still outstanding question whether Ge atoms prefer to intercalate between the MoS2 layers or rather form germanene islands on top of the MoS2 substrate. We found that, at a fixed growth temperature, germanene islands are formed on top of the MoS2 substrate at high deposition rates, whereas at low deposition rates the Ge intercalates between the MoS2 layers. Scanning tunneling spectra recorded on the germanene islands reveal a V-shaped density of states, which is one of the hallmarks of a two-dimensional Dirac material. The intercalated Ge clusters have a band gap of 0.5-0.6 eV. Density functional theory calculations have been conducted in order to study the stability and electronic band structure of several intercalated Ge cluster configurations. Based on these calculations we are able to identify two promising stable configurations that have a band gap that compares favorably well with the experimental observations. Scanning tunneling spectroscopy measurement recorded on the intercalated Ge clusters reveals signatures of Coulomb blockade.

Original languageEnglish
Article number205419
JournalPhysical review B: Covering condensed matter and materials physics
Issue number20
Publication statusPublished - 16 Nov 2020


Dive into the research topics of 'Germanium/MoS2: Competition between the growth of germanene and intercalation'. Together they form a unique fingerprint.

Cite this