Grid forming metal coordinating macroligands: Synthesis and complexation

Richard Hoogenboom, Jurriaan Huskens, Ulrich S. Schubert*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

5 Citations (Scopus)

Abstract

The synthesis of poly(L-lactide) ewpyridylpyridazine macroligands from a hydroxyl functionalized ligand by controlled ring-opening polymerization is described. The resulting macroligands were characterized by 1H-NMR spectroscopy, GPC and MALDI-TOF MS. The metal coordination of those macroligands with copper(I) resulting in polymeric [2×2] metal grids was investigated by UV-vis titration studies. In addition, the complexation behavior obtained from these experiments was modeled in order to explore the complexation parameters and the corresponding mechanism.

Original languageEnglish
Title of host publicationMetal-Containing and Metallosupramolecular Polymers and Materials
EditorsUlrich Schubert, George Newkome, Ian Manners
Pages63-71
Number of pages9
DOIs
Publication statusPublished - 23 Mar 2006

Publication series

NameACS Symposium Series
Volume928
ISSN (Print)0097-6156

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