Halophilic polysulfabetaines-synthesis and study of gelation and thermoresponsive behavior

Vivek Arjunan Vasantha, Satyasankar Jana, Anbanandam Parthiban, Julius G. Vancso

Research output: Contribution to journalArticleAcademicpeer-review

23 Citations (Scopus)
53 Downloads (Pure)

Abstract

Polysulfabetaines (PSBs) derived from zwitterionic sulfates (contrary to commonly used polysulfobetaines which are derived from zwitterionic sulfonates) were synthesized for the first time. PSBs dissolved in brine (halophilic), swelled in deionized water and also exhibited reversible and irreversible thermoresponsive behavior. Large differences in interaction with deionized water and brine solution as well as morphology of particles in dispersion was observed between poly[2-(dimethyl(4-vinylbenzyl)ammonio)ethyl sulfate] (PSB 1) and poly[3-(dimethyl(4-vinylbenzyl)ammonio)propyl sulfate] (PSB 2) even though a single methylene (-CH 2 -) unit was the sole differentiating factor. The gelation and thermoresponsive behaviour observed in PSBs are similar to that of naturally occurring polymers. This journal is
Original languageEnglish
Pages (from-to)22596-22600
Number of pages5
JournalRSC advances
Volume4
Issue number43
DOIs
Publication statusPublished - 1 Jan 2014

Fingerprint Dive into the research topics of 'Halophilic polysulfabetaines-synthesis and study of gelation and thermoresponsive behavior'. Together they form a unique fingerprint.

Cite this