High permeable PTMSP/PAN composite membranes for solvent nanofiltration

A.V. Volkov; Alexey V. Volkov; Victor V. Parashchuk; Dimitrios Stamatialis; Valery S. Khotimsky; Vladimir V. Volkov; Matthias Wessling

doi:10.1016/j.memsci.2009.01.050

High permeable PTMSP/PAN composite membranes for solvent nanofiltration

A.V. Volkov, Alexey V. Volkov, Victor V. Parashchuk, Dimitrios Stamatialis, Valery S. Khotimsky, Vladimir V. Volkov, Matthias Wessling

Research output: Contribution to journal › Article › Academic › peer-review

93 Citations (Scopus)

Abstract

This paper describes the preparation of composite membranes comprising a poly[1-(trimethylsilyl)-1-propyne] (PTMSP) top-layer on a porous poly(acrylonitrile) (PAN) support. The PTMSP layer has different top-layer thickness in the range of 0.7–6.3 μm. The optimized PTMSP/PAN composite membranes with top-layer thickness of about 1 μm have ethanol permeability of 3.8 kg/(m2 h bar) and 90% retention of the negatively charged dye Remazol Brilliant Blue R (MW 626.5) at 5 bar. The permeability of methanol, ethanol or acetone through the PTMSP/PAN composite membranes is higher than a number of commercial available nanofiltration membranes, whereas all membranes have rejection of about 90% for negative charged dyes of different molecular weight. The permeability of methanol, ethanol and acetone through the PTMSP/PAN composite membranes depends on solvent viscosity and membrane swelling; the solvent viscosity seems to be the dominant factor.

Original language	Undefined
Pages (from-to)	88-93
Journal	Journal of membrane science
Volume	333
Issue number	1-2
DOIs	https://doi.org/10.1016/j.memsci.2009.01.050
Publication status	Published - 2009

Keywords

IR-71530
METIS-256410

Access to Document

10.1016/j.memsci.2009.01.050

Cite this

@article{34e1640d261b406aa9f135395a366052,

title = "High permeable PTMSP/PAN composite membranes for solvent nanofiltration",

abstract = "This paper describes the preparation of composite membranes comprising a poly[1-(trimethylsilyl)-1-propyne] (PTMSP) top-layer on a porous poly(acrylonitrile) (PAN) support. The PTMSP layer has different top-layer thickness in the range of 0.7–6.3 μm. The optimized PTMSP/PAN composite membranes with top-layer thickness of about 1 μm have ethanol permeability of 3.8 kg/(m2 h bar) and 90% retention of the negatively charged dye Remazol Brilliant Blue R (MW 626.5) at 5 bar. The permeability of methanol, ethanol or acetone through the PTMSP/PAN composite membranes is higher than a number of commercial available nanofiltration membranes, whereas all membranes have rejection of about 90% for negative charged dyes of different molecular weight. The permeability of methanol, ethanol and acetone through the PTMSP/PAN composite membranes depends on solvent viscosity and membrane swelling; the solvent viscosity seems to be the dominant factor.",

keywords = "IR-71530, METIS-256410",

author = "A.V. Volkov and Volkov, {Alexey V.} and Parashchuk, {Victor V.} and Dimitrios Stamatialis and Khotimsky, {Valery S.} and Volkov, {Vladimir V.} and Matthias Wessling",

year = "2009",

doi = "10.1016/j.memsci.2009.01.050",

language = "Undefined",

volume = "333",

pages = "88--93",

journal = "Journal of membrane science",

issn = "0376-7388",

publisher = "Elsevier",

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TY - JOUR

T1 - High permeable PTMSP/PAN composite membranes for solvent nanofiltration

AU - Volkov, A.V.

AU - Volkov, Alexey V.

AU - Parashchuk, Victor V.

AU - Stamatialis, Dimitrios

AU - Khotimsky, Valery S.

AU - Volkov, Vladimir V.

AU - Wessling, Matthias

PY - 2009

Y1 - 2009

N2 - This paper describes the preparation of composite membranes comprising a poly[1-(trimethylsilyl)-1-propyne] (PTMSP) top-layer on a porous poly(acrylonitrile) (PAN) support. The PTMSP layer has different top-layer thickness in the range of 0.7–6.3 μm. The optimized PTMSP/PAN composite membranes with top-layer thickness of about 1 μm have ethanol permeability of 3.8 kg/(m2 h bar) and 90% retention of the negatively charged dye Remazol Brilliant Blue R (MW 626.5) at 5 bar. The permeability of methanol, ethanol or acetone through the PTMSP/PAN composite membranes is higher than a number of commercial available nanofiltration membranes, whereas all membranes have rejection of about 90% for negative charged dyes of different molecular weight. The permeability of methanol, ethanol and acetone through the PTMSP/PAN composite membranes depends on solvent viscosity and membrane swelling; the solvent viscosity seems to be the dominant factor.

AB - This paper describes the preparation of composite membranes comprising a poly[1-(trimethylsilyl)-1-propyne] (PTMSP) top-layer on a porous poly(acrylonitrile) (PAN) support. The PTMSP layer has different top-layer thickness in the range of 0.7–6.3 μm. The optimized PTMSP/PAN composite membranes with top-layer thickness of about 1 μm have ethanol permeability of 3.8 kg/(m2 h bar) and 90% retention of the negatively charged dye Remazol Brilliant Blue R (MW 626.5) at 5 bar. The permeability of methanol, ethanol or acetone through the PTMSP/PAN composite membranes is higher than a number of commercial available nanofiltration membranes, whereas all membranes have rejection of about 90% for negative charged dyes of different molecular weight. The permeability of methanol, ethanol and acetone through the PTMSP/PAN composite membranes depends on solvent viscosity and membrane swelling; the solvent viscosity seems to be the dominant factor.

KW - IR-71530

KW - METIS-256410

U2 - 10.1016/j.memsci.2009.01.050

DO - 10.1016/j.memsci.2009.01.050

M3 - Article

SN - 0376-7388

VL - 333

SP - 88

EP - 93

JO - Journal of membrane science

JF - Journal of membrane science

IS - 1-2

ER -