TY - JOUR
T1 - High-temperature compressive creep behaviour of perovskite-type oxides SrTi1-xFexO3-δ
AU - ten Donkelaar, S.F.P.
AU - Stournari, V.
AU - Malzbender, J.
AU - Nijmeijer, Arian
AU - Bouwmeester, Henricus J.M.
PY - 2015
Y1 - 2015
N2 - Compressive creep tests have been performed on mixed ionic-electronic conducting perovskite-type oxides SrTi1-xFexO3- (STF, x = 0.3, 0.5 and 0.7). Observed activation energies and stress exponents, at 800–1000 ◦C and in the stress range 10 100 MPa, indicate that the steady-state creep rate of STF under these conditions is predominantly limited by cation lattice diffusion (Nabarro-Herring creep). The effective stress exponents reflect a contribution of dislocation creep to the mechanism of creep in STF30 (x = 0.3). The observed creep rates are compared with those exhibited by related perovskite-type oxides, and are discussed in view of the possible application of STF as oxygen transport membrane (OTM).
AB - Compressive creep tests have been performed on mixed ionic-electronic conducting perovskite-type oxides SrTi1-xFexO3- (STF, x = 0.3, 0.5 and 0.7). Observed activation energies and stress exponents, at 800–1000 ◦C and in the stress range 10 100 MPa, indicate that the steady-state creep rate of STF under these conditions is predominantly limited by cation lattice diffusion (Nabarro-Herring creep). The effective stress exponents reflect a contribution of dislocation creep to the mechanism of creep in STF30 (x = 0.3). The observed creep rates are compared with those exhibited by related perovskite-type oxides, and are discussed in view of the possible application of STF as oxygen transport membrane (OTM).
KW - IR-99491
KW - METIS-315948
U2 - 10.1016/j.jeurceramsoc.2015.08.002
DO - 10.1016/j.jeurceramsoc.2015.08.002
M3 - Article
VL - 35
SP - 4203
EP - 4209
JO - Journal of the European Ceramic Society
JF - Journal of the European Ceramic Society
SN - 0955-2219
ER -