Highly Conductive and Broadband Transparent Zr-Doped In2O3 as Front Electrode for Solar Cells

Monica Morales-Masis, Esteban Rucavado, Raphaël Monnard, Loris Barraud, Jakub Holovský, Matthieu Despeisse, Mathieu Boccard, Christophe Ballif

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Abstract

Broadband transparent and highly conducting electrodes are key to avoid parasitic absorption and electrical losses in solar cells. Here, we propose zirconium-doped indium oxide (IO:Zr) as a transparent electrode intrinsically meeting both requirements and demonstrate its application as the front electrode in silicon heterojunction (SHJ) solar cells. The exceptional properties of this material rely on the combination of high-doping and high electron mobilities, achieving with this a wide optical band gap (3.5–4 eV), low free carrier absorption, and high lateral conductivity. A single film of IO:Zr has an electron mobility of 100 cm2/Vcs with a carrier density of 2.5–3 × 1020 cm–3, resulting in a sheet resistance of around 25 Ω/sq for 100-nm-thick films. Their implementation as a front electrode in SHJ solar cells results in an important gain in current density as compared to the standardly used Sn-doped indium oxide. This is due to reduced parasitic absorption in both, the UV and IR, as confirmed by external quantum efficiency measurements. SHJ devices with the optimized IO:Zr front electrode, resulting in current densities of 40 mA/cm2, a fill factor of 80%, and a conversion efficiency of 23.4%.

Original languageEnglish
Article number8410059
Pages (from-to)1202-1207
Number of pages6
JournalIEEE journal of photovoltaics
Volume8
Issue number5
Early online date11 Jul 2018
DOIs
Publication statusPublished - 1 Sep 2018

Fingerprint

Solar cells
solar cells
broadband
Silicon
Electrodes
electrodes
Heterojunctions
Electron mobility
electron mobility
indium oxides
Indium
heterojunctions
silicon
Current density
current density
heterojunction devices
Oxides
Sheet resistance
Optical band gaps
Quantum efficiency

Keywords

  • Electron mobility
  • Heterojunctions
  • Silicon
  • Solar cells
  • Transparent electrodes
  • Wide band gap semiconductors
  • Zirconium-doped indium oxide (IO:Zr)

Cite this

Morales-Masis, M., Rucavado, E., Monnard, R., Barraud, L., Holovský, J., Despeisse, M., ... Ballif, C. (2018). Highly Conductive and Broadband Transparent Zr-Doped In2O3 as Front Electrode for Solar Cells. IEEE journal of photovoltaics, 8(5), 1202-1207. [8410059]. https://doi.org/10.1109/JPHOTOV.2018.2851306
Morales-Masis, Monica ; Rucavado, Esteban ; Monnard, Raphaël ; Barraud, Loris ; Holovský, Jakub ; Despeisse, Matthieu ; Boccard, Mathieu ; Ballif, Christophe. / Highly Conductive and Broadband Transparent Zr-Doped In2O3 as Front Electrode for Solar Cells. In: IEEE journal of photovoltaics. 2018 ; Vol. 8, No. 5. pp. 1202-1207.
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abstract = "Broadband transparent and highly conducting electrodes are key to avoid parasitic absorption and electrical losses in solar cells. Here, we propose zirconium-doped indium oxide (IO:Zr) as a transparent electrode intrinsically meeting both requirements and demonstrate its application as the front electrode in silicon heterojunction (SHJ) solar cells. The exceptional properties of this material rely on the combination of high-doping and high electron mobilities, achieving with this a wide optical band gap (3.5–4 eV), low free carrier absorption, and high lateral conductivity. A single film of IO:Zr has an electron mobility of 100 cm2/Vcs with a carrier density of 2.5–3 × 1020 cm–3, resulting in a sheet resistance of around 25 Ω/sq for 100-nm-thick films. Their implementation as a front electrode in SHJ solar cells results in an important gain in current density as compared to the standardly used Sn-doped indium oxide. This is due to reduced parasitic absorption in both, the UV and IR, as confirmed by external quantum efficiency measurements. SHJ devices with the optimized IO:Zr front electrode, resulting in current densities of 40 mA/cm2, a fill factor of 80{\%}, and a conversion efficiency of 23.4{\%}.",
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Morales-Masis, M, Rucavado, E, Monnard, R, Barraud, L, Holovský, J, Despeisse, M, Boccard, M & Ballif, C 2018, 'Highly Conductive and Broadband Transparent Zr-Doped In2O3 as Front Electrode for Solar Cells' IEEE journal of photovoltaics, vol. 8, no. 5, 8410059, pp. 1202-1207. https://doi.org/10.1109/JPHOTOV.2018.2851306

Highly Conductive and Broadband Transparent Zr-Doped In2O3 as Front Electrode for Solar Cells. / Morales-Masis, Monica; Rucavado, Esteban; Monnard, Raphaël; Barraud, Loris; Holovský, Jakub; Despeisse, Matthieu; Boccard, Mathieu; Ballif, Christophe.

In: IEEE journal of photovoltaics, Vol. 8, No. 5, 8410059, 01.09.2018, p. 1202-1207.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Highly Conductive and Broadband Transparent Zr-Doped In2O3 as Front Electrode for Solar Cells

AU - Morales-Masis, Monica

AU - Rucavado, Esteban

AU - Monnard, Raphaël

AU - Barraud, Loris

AU - Holovský, Jakub

AU - Despeisse, Matthieu

AU - Boccard, Mathieu

AU - Ballif, Christophe

PY - 2018/9/1

Y1 - 2018/9/1

N2 - Broadband transparent and highly conducting electrodes are key to avoid parasitic absorption and electrical losses in solar cells. Here, we propose zirconium-doped indium oxide (IO:Zr) as a transparent electrode intrinsically meeting both requirements and demonstrate its application as the front electrode in silicon heterojunction (SHJ) solar cells. The exceptional properties of this material rely on the combination of high-doping and high electron mobilities, achieving with this a wide optical band gap (3.5–4 eV), low free carrier absorption, and high lateral conductivity. A single film of IO:Zr has an electron mobility of 100 cm2/Vcs with a carrier density of 2.5–3 × 1020 cm–3, resulting in a sheet resistance of around 25 Ω/sq for 100-nm-thick films. Their implementation as a front electrode in SHJ solar cells results in an important gain in current density as compared to the standardly used Sn-doped indium oxide. This is due to reduced parasitic absorption in both, the UV and IR, as confirmed by external quantum efficiency measurements. SHJ devices with the optimized IO:Zr front electrode, resulting in current densities of 40 mA/cm2, a fill factor of 80%, and a conversion efficiency of 23.4%.

AB - Broadband transparent and highly conducting electrodes are key to avoid parasitic absorption and electrical losses in solar cells. Here, we propose zirconium-doped indium oxide (IO:Zr) as a transparent electrode intrinsically meeting both requirements and demonstrate its application as the front electrode in silicon heterojunction (SHJ) solar cells. The exceptional properties of this material rely on the combination of high-doping and high electron mobilities, achieving with this a wide optical band gap (3.5–4 eV), low free carrier absorption, and high lateral conductivity. A single film of IO:Zr has an electron mobility of 100 cm2/Vcs with a carrier density of 2.5–3 × 1020 cm–3, resulting in a sheet resistance of around 25 Ω/sq for 100-nm-thick films. Their implementation as a front electrode in SHJ solar cells results in an important gain in current density as compared to the standardly used Sn-doped indium oxide. This is due to reduced parasitic absorption in both, the UV and IR, as confirmed by external quantum efficiency measurements. SHJ devices with the optimized IO:Zr front electrode, resulting in current densities of 40 mA/cm2, a fill factor of 80%, and a conversion efficiency of 23.4%.

KW - Electron mobility

KW - Heterojunctions

KW - Silicon

KW - Solar cells

KW - Transparent electrodes

KW - Wide band gap semiconductors

KW - Zirconium-doped indium oxide (IO:Zr)

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DO - 10.1109/JPHOTOV.2018.2851306

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EP - 1207

JO - IEEE journal of photovoltaics

JF - IEEE journal of photovoltaics

SN - 2156-3381

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ER -