Highly ordered films of neat calix[4]arenes for second nonlinear optics

Erik Kelderman; Gerard J.T. Heesink; Lode Derhaeg; Thierry Verbiest; Piet T.A. Klaase; Willem Verboom; Johan F.J. Engbersen; Niek F. van Hulst; Koen Clays; Andre Persoons; David N. Reinhoudt

doi:10.1002/adma.19930051211

Highly ordered films of neat calix[4]arenes for second nonlinear optics

Erik Kelderman, Gerard J.T. Heesink, Lode Derhaeg, Thierry Verbiest, Piet T.A. Klaase, Willem Verboom, Johan F.J. Engbersen, Niek F. van Hulst, Koen Clays, Andre Persoons, David N. Reinhoudt

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Abstract

In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.

Original language	English
Pages (from-to)	925-930
Journal	Advanced materials
Volume	5
Issue number	12
DOIs	https://doi.org/10.1002/adma.19930051211
Publication status	Published - 1993

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@article{f425e362ffd24439bc4b0d56973f52bb,

title = "Highly ordered films of neat calix[4]arenes for second nonlinear optics",

abstract = "In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.",

author = "Erik Kelderman and Heesink, {Gerard J.T.} and Lode Derhaeg and Thierry Verbiest and Klaase, {Piet T.A.} and Willem Verboom and Engbersen, {Johan F.J.} and {van Hulst}, {Niek F.} and Koen Clays and Andre Persoons and Reinhoudt, {David N.}",

year = "1993",

doi = "10.1002/adma.19930051211",

language = "English",

volume = "5",

pages = "925--930",

journal = "Advanced materials",

issn = "0935-9648",

publisher = "Wiley-Blackwell",

number = "12",

}

TY - JOUR

T1 - Highly ordered films of neat calix[4]arenes for second nonlinear optics

AU - Kelderman, Erik

AU - Heesink, Gerard J.T.

AU - Derhaeg, Lode

AU - Verbiest, Thierry

AU - Klaase, Piet T.A.

AU - Verboom, Willem

AU - Engbersen, Johan F.J.

AU - van Hulst, Niek F.

AU - Clays, Koen

AU - Persoons, Andre

AU - Reinhoudt, David N.

PY - 1993

Y1 - 1993

N2 - In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.

AB - In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.

U2 - 10.1002/adma.19930051211

DO - 10.1002/adma.19930051211

M3 - Article

SN - 0935-9648

VL - 5

SP - 925

EP - 930

JO - Advanced materials

JF - Advanced materials

IS - 12

ER -

Highly ordered films of neat calix[4]arenes for second nonlinear optics

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