Highly ordered films of neat calix[4]arenes for second nonlinear optics

Erik Kelderman; Gerard J.T. Heesink; Lode Derhaeg; Thierry Verbiest; Piet T.A. Klaase; Willem Verboom; Johan F.J. Engbersen; Niek F. van Hulst; Koen Clays; Andre Persoons; David N. Reinhoudt

doi:10.1002/adma.19930051211

Highly ordered films of neat calix[4]arenes for second nonlinear optics

Erik Kelderman
, Gerard J.T. Heesink
, Lode Derhaeg
, Thierry Verbiest
, Piet T.A. Klaase
, Willem Verboom
, Johan F.J. Engbersen
, Niek F. van Hulst
, Koen Clays
, Andre Persoons
, David N. Reinhoudt

Research output: Contribution to journal › Article › Academic › peer-review

40 Citations (Scopus)

256 Downloads (Pure)

Abstract

In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.

Original language	English
Pages (from-to)	925-930
Journal	Advanced materials
Volume	5
Issue number	12
DOIs	https://doi.org/10.1002/adma.19930051211
Publication status	Published - 1993

Access to Document

10.1002/adma.19930051211

Kelderman1993highlyFinal published version, 632 KB

Cite this

@article{f425e362ffd24439bc4b0d56973f52bb,

title = "Highly ordered films of neat calix[4]arenes for second nonlinear optics",

abstract = "In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.",

author = "Erik Kelderman and Heesink, \{Gerard J.T.\} and Lode Derhaeg and Thierry Verbiest and Klaase, \{Piet T.A.\} and Willem Verboom and Engbersen, \{Johan F.J.\} and \{van Hulst\}, \{Niek F.\} and Koen Clays and Andre Persoons and Reinhoudt, \{David N.\}",

year = "1993",

doi = "10.1002/adma.19930051211",

language = "English",

volume = "5",

pages = "925--930",

journal = "Advanced materials",

issn = "0935-9648",

publisher = "Wiley-Blackwell",

number = "12",

}

TY - JOUR

T1 - Highly ordered films of neat calix[4]arenes for second nonlinear optics

AU - Kelderman, Erik

AU - Heesink, Gerard J.T.

AU - Derhaeg, Lode

AU - Verbiest, Thierry

AU - Klaase, Piet T.A.

AU - Verboom, Willem

AU - Engbersen, Johan F.J.

AU - van Hulst, Niek F.

AU - Clays, Koen

AU - Persoons, Andre

AU - Reinhoudt, David N.

PY - 1993

Y1 - 1993

N2 - In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.

AB - In substituted calix[4]-arenes-cyclophanes consisting of four phenol moieties connected by methylene bridges-the number and also the relative positions of the donor and/or acceptor pi- conjugated (D-pi-A) units can be varied by changing the configuration. The Figure illustrates the cone configuration. The molecular and thin-film NLO properties of three tetra-D-pi- A-substituted calix[4]arenes, including their orientation in thin films and the stability of their NLO properties, are described.

U2 - 10.1002/adma.19930051211

DO - 10.1002/adma.19930051211

M3 - Article

SN - 0935-9648

VL - 5

SP - 925

EP - 930

JO - Advanced materials

JF - Advanced materials

IS - 12

ER -

Highly ordered films of neat calix[4]arenes for second nonlinear optics

Abstract

Access to Document

Fingerprint

Cite this