Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases

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Abstract

Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS−imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.
Original languageEnglish
Pages (from-to)3660-3664
JournalChemistry of materials
Volume26
DOIs
Publication statusPublished - 2014

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Imides
Gases
Membranes
Gas permeability
Rigidity
Tuning
Temperature

Keywords

  • METIS-309128
  • IR-94184

Cite this

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title = "Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases",
abstract = "Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS−imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.",
keywords = "METIS-309128, IR-94184",
author = "Michiel Raaijmakers and Matthias Wessling and Arian Nijmeijer and Benes, {Nieck Edwin}",
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doi = "10.1021/cm500691e",
language = "English",
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pages = "3660--3664",
journal = "Chemistry of materials",
issn = "0897-4756",
publisher = "American Chemical Society",

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Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases. / Raaijmakers, Michiel; Wessling, Matthias; Nijmeijer, Arian; Benes, Nieck Edwin.

In: Chemistry of materials, Vol. 26, 2014, p. 3660-3664.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases

AU - Raaijmakers, Michiel

AU - Wessling, Matthias

AU - Nijmeijer, Arian

AU - Benes, Nieck Edwin

PY - 2014

Y1 - 2014

N2 - Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS−imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.

AB - Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS−imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.

KW - METIS-309128

KW - IR-94184

U2 - 10.1021/cm500691e

DO - 10.1021/cm500691e

M3 - Article

VL - 26

SP - 3660

EP - 3664

JO - Chemistry of materials

JF - Chemistry of materials

SN - 0897-4756

ER -