Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases

Michiel J.T. Raaijmakers; Matthias Wessling; Arian Nijmeijer; Nieck E. Benes

doi:10.1021/cm500691e

Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases

Michiel J.T. Raaijmakers
, Matthias Wessling
, Arian Nijmeijer
, Nieck E. Benes^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

30 Citations (Scopus)

352 Downloads (Pure)

Abstract

Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS−imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.

Original language	English
Pages (from-to)	3660-3664
Journal	Chemistry of materials
Volume	26
DOIs	https://doi.org/10.1021/cm500691e
Publication status	Published - 2014

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2023 OA procedure

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10.1021/cm500691e

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title = "Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases",

abstract = "Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS−imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.",

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journal = "Chemistry of materials",

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AU - Raaijmakers, Michiel J.T.

AU - Wessling, Matthias

AU - Nijmeijer, Arian

AU - Benes, Nieck E.

PY - 2014

Y1 - 2014

N2 - Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS−imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.

AB - Macromolecular network rigidity of synthetic membranes is essential for sieving of hot gases. Hyper-cross-linked polyPOSS−imide membranes with tailored intercage spacing are presented. The length and flexibility of their imide bridges enables tuning of gas permeability and selectivity in a broad temperature range. The facile synthesis allows for large-scale production of membranes designed for specific process conditions.

KW - 2023 OA procedure

U2 - 10.1021/cm500691e

DO - 10.1021/cm500691e

M3 - Article

SN - 0897-4756

VL - 26

SP - 3660

EP - 3664

JO - Chemistry of materials

JF - Chemistry of materials

ER -

Hybrid Polyhedral Oligomeric Silsesquioxanes-Imides with Tailored Intercage Spacing for Sieving of Hot Gases

Abstract

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