Hydrogen adsorption configurations on Ge(001)probed with STM

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Abstract

The adsorption of hydrogen on Ge(001) has been studied with scanning tunneling microscopy at 77 K. For low doses (100 L) a variety of adsorption structures has been found. We have found two different atomic configurations for the Ge-Ge-H hemihydride and a third configuration that is most likely induced by the dissociative adsorption of molecular hydrogen. The Ge-Ge-H hemihydride is either buckled antiparallel or parallel to the neighboring Ge-Ge dimers. The latter configuration has recently been predicted by M. W. Radny et al. [J. Chem. Phys. 128, 244707 (2008)], but not observed experimentally yet. Due to the presence of phasons some dimer rows appear highly dynamic.
Original languageEnglish
Pages (from-to)153402-
Number of pages4
JournalPhysical review B: Condensed matter and materials physics
Volume79
Issue number15
DOIs
Publication statusPublished - 2009

Keywords

  • Elemental semiconductors
  • Dissociation
  • Adsorption
  • Germanium
  • Scanning tunnelling microscopy
  • Hydrogen
  • 2024 OA procedure

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