Abstract
Life is branched! Statistically branched (=hyperbranched) polymers have become an important class of materials in modern chemistry. Not only due to straightforward synthetic approaches which were developed in the last decade but also due to the vast amount of available monomers, hyperbranched polymers have replaced perfect dendrimers in many areas and they will have an even higher impact in future. This chapter highlights classic and modern syntheses of hyperbranched polymers and their unique properties and presents their versatility in the macromolecular toolbox for the design of complex nonlinear architectures.
Original language | English |
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Title of host publication | Polymer Science |
Subtitle of host publication | A Comprehensive Reference, 10 Volume Set |
Publisher | Elsevier |
Pages | 177-198 |
Number of pages | 22 |
Volume | 6 |
ISBN (Print) | 9780080878621 |
DOIs | |
Publication status | Published - 1 Dec 2012 |
Externally published | Yes |
Keywords
- Degree of branching
- Dendrimer
- Hyperbranched polymers
- Inimer
- Linear hyperbranched block copolymers
- Polycondensation
- Ring-opening multibranching polymerization
- Self-condensing
- Star polymers