b-Oriented MFI membranes prepared from porous silica coatings

Sonia Aguado; E.E. McLeary; Arian Nijmeijer; Mieke Luiten; Jacobus C. Jansen; Freek Kapteijn

doi:10.1016/j.micromeso.2008.08.059

b-Oriented MFI membranes prepared from porous silica coatings

Sonia Aguado^*
, E.E. McLeary
, Arian Nijmeijer
, Mieke Luiten
, Jacobus C. Jansen
, Freek Kapteijn

^*Corresponding author for this work

Inorganic Membranes

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The preparation of b-oriented MFI films from porous silica layers was investigated and optimized. The alumina supported silica membranes were immersed in a concentrated TPAOH solution. Finally b-oriented and well-intergrown MFI crystal films were produced by carrying out an in situ hydrothermal synthesis using a synthesis solution 1 SiO₂:0.05 TPAOH:37.5–169 H₂O:0.15 NaOH. The main function of the silica is twofold, it serves as a nucleation layer for the silicalite-1 and provides a smooth surface for the oriented crystal growth into a continuous layer. Prolonged synthesis duration leads to the formation of a secondary layer with increasing α-orientation.

Original language	English
Pages (from-to)	165-169
Journal	Microporous and mesoporous materials
Volume	120
Issue number	1-2
DOIs	https://doi.org/10.1016/j.micromeso.2008.08.059
Publication status	Published - 2009

Keywords

MFI
Zeolite
In situ crystallization
Film
Orientation
2023 OA procedure

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10.1016/j.micromeso.2008.08.059

ArticleFinal published version, 486 KBLicence: Taverne

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title = "b-Oriented MFI membranes prepared from porous silica coatings",

abstract = "The preparation of b-oriented MFI films from porous silica layers was investigated and optimized. The alumina supported silica membranes were immersed in a concentrated TPAOH solution. Finally b-oriented and well-intergrown MFI crystal films were produced by carrying out an in situ hydrothermal synthesis using a synthesis solution 1 SiO2:0.05 TPAOH:37.5{\textendash}169 H2O:0.15 NaOH. The main function of the silica is twofold, it serves as a nucleation layer for the silicalite-1 and provides a smooth surface for the oriented crystal growth into a continuous layer. Prolonged synthesis duration leads to the formation of a secondary layer with increasing α-orientation.",

keywords = "MFI, Zeolite, In situ crystallization, Film, Orientation, 2023 OA procedure",

author = "Sonia Aguado and E.E. McLeary and Arian Nijmeijer and Mieke Luiten and Jansen, \{Jacobus C.\} and Freek Kapteijn",

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language = "English",

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T1 - b-Oriented MFI membranes prepared from porous silica coatings

AU - Aguado, Sonia

AU - McLeary, E.E.

AU - Nijmeijer, Arian

AU - Luiten, Mieke

AU - Jansen, Jacobus C.

AU - Kapteijn, Freek

PY - 2009

Y1 - 2009

N2 - The preparation of b-oriented MFI films from porous silica layers was investigated and optimized. The alumina supported silica membranes were immersed in a concentrated TPAOH solution. Finally b-oriented and well-intergrown MFI crystal films were produced by carrying out an in situ hydrothermal synthesis using a synthesis solution 1 SiO2:0.05 TPAOH:37.5–169 H2O:0.15 NaOH. The main function of the silica is twofold, it serves as a nucleation layer for the silicalite-1 and provides a smooth surface for the oriented crystal growth into a continuous layer. Prolonged synthesis duration leads to the formation of a secondary layer with increasing α-orientation.

AB - The preparation of b-oriented MFI films from porous silica layers was investigated and optimized. The alumina supported silica membranes were immersed in a concentrated TPAOH solution. Finally b-oriented and well-intergrown MFI crystal films were produced by carrying out an in situ hydrothermal synthesis using a synthesis solution 1 SiO2:0.05 TPAOH:37.5–169 H2O:0.15 NaOH. The main function of the silica is twofold, it serves as a nucleation layer for the silicalite-1 and provides a smooth surface for the oriented crystal growth into a continuous layer. Prolonged synthesis duration leads to the formation of a secondary layer with increasing α-orientation.

KW - MFI

KW - Zeolite

KW - In situ crystallization

KW - Film

KW - Orientation

KW - 2023 OA procedure

U2 - 10.1016/j.micromeso.2008.08.059

DO - 10.1016/j.micromeso.2008.08.059

M3 - Article

SN - 1387-1811

VL - 120

SP - 165

EP - 169

JO - Microporous and mesoporous materials

JF - Microporous and mesoporous materials

IS - 1-2

ER -

b-Oriented MFI membranes prepared from porous silica coatings

Abstract

Keywords

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