Improved Langmuir−Blodgett titanate films via in situ exfoliation study and optimization of deposition parameters

H. Yuan, R. Lubbers, R. Besselink, Maarten Nijland, Johan E. ten Elshof

Research output: Contribution to journalArticleAcademicpeer-review

23 Citations (Scopus)

Abstract

The exfoliation and deposition of large (10–100 μm) Ti0.87O2 and small (0.1–1 μm) Ti0.91O2 nanosheets from lepidocrocite-type protonated titanates was investigated for getting high quality films. Exfoliation was carried out with different tetra-alkyl ammonium ions (TAA+) and varying TAA+/H+ ratios, and the colloidal solutions were characterized by small-angle X-ray scattering (SAXS) and ultraviolet–visible (UV–vis) spectroscopy. Using Langmuir-Blodgett deposition the titanate nanosheets were directly transferred onto a Si substrate. The resulting films were characterized by atomic force microscopy (AFM).The results indicate that the H1.07Ti1.73O4 titanate exfoliated at very low ratios of TAA+/H+; no lower threshold for exfoliation was observed for the TAA+ concentration. Nanosheets exfoliated at very low ratios of TAA+/H+ typically showed a small size and porous surface. Subsequent exfoliation of the remaining layered titanate particles yielded much higher quality nanosheets. The optimized deposition parameters for Langmuir-Blodgett films suggest that the surface pressure is a key parameter to control the coverage of the film. The bulk concentration of nanosheets was found to be a less important deposition parameter in the LB deposition process. It only influenced whether the desired surface pressure could be reached at a given maximum degree of compression.
Original languageUndefined
Pages (from-to)8567-8574
Number of pages8
JournalACS applied materials & interfaces
Volume6
Issue number11
DOIs
Publication statusPublished - 2014

Keywords

  • METIS-303774
  • IR-94875

Cite this

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title = "Improved Langmuir−Blodgett titanate films via in situ exfoliation study and optimization of deposition parameters",
abstract = "The exfoliation and deposition of large (10–100 μm) Ti0.87O2 and small (0.1–1 μm) Ti0.91O2 nanosheets from lepidocrocite-type protonated titanates was investigated for getting high quality films. Exfoliation was carried out with different tetra-alkyl ammonium ions (TAA+) and varying TAA+/H+ ratios, and the colloidal solutions were characterized by small-angle X-ray scattering (SAXS) and ultraviolet–visible (UV–vis) spectroscopy. Using Langmuir-Blodgett deposition the titanate nanosheets were directly transferred onto a Si substrate. The resulting films were characterized by atomic force microscopy (AFM).The results indicate that the H1.07Ti1.73O4 titanate exfoliated at very low ratios of TAA+/H+; no lower threshold for exfoliation was observed for the TAA+ concentration. Nanosheets exfoliated at very low ratios of TAA+/H+ typically showed a small size and porous surface. Subsequent exfoliation of the remaining layered titanate particles yielded much higher quality nanosheets. The optimized deposition parameters for Langmuir-Blodgett films suggest that the surface pressure is a key parameter to control the coverage of the film. The bulk concentration of nanosheets was found to be a less important deposition parameter in the LB deposition process. It only influenced whether the desired surface pressure could be reached at a given maximum degree of compression.",
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Improved Langmuir−Blodgett titanate films via in situ exfoliation study and optimization of deposition parameters. / Yuan, H.; Lubbers, R.; Besselink, R.; Nijland, Maarten; ten Elshof, Johan E.

In: ACS applied materials & interfaces, Vol. 6, No. 11, 2014, p. 8567-8574.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Improved Langmuir−Blodgett titanate films via in situ exfoliation study and optimization of deposition parameters

AU - Yuan, H.

AU - Lubbers, R.

AU - Besselink, R.

AU - Nijland, Maarten

AU - ten Elshof, Johan E.

PY - 2014

Y1 - 2014

N2 - The exfoliation and deposition of large (10–100 μm) Ti0.87O2 and small (0.1–1 μm) Ti0.91O2 nanosheets from lepidocrocite-type protonated titanates was investigated for getting high quality films. Exfoliation was carried out with different tetra-alkyl ammonium ions (TAA+) and varying TAA+/H+ ratios, and the colloidal solutions were characterized by small-angle X-ray scattering (SAXS) and ultraviolet–visible (UV–vis) spectroscopy. Using Langmuir-Blodgett deposition the titanate nanosheets were directly transferred onto a Si substrate. The resulting films were characterized by atomic force microscopy (AFM).The results indicate that the H1.07Ti1.73O4 titanate exfoliated at very low ratios of TAA+/H+; no lower threshold for exfoliation was observed for the TAA+ concentration. Nanosheets exfoliated at very low ratios of TAA+/H+ typically showed a small size and porous surface. Subsequent exfoliation of the remaining layered titanate particles yielded much higher quality nanosheets. The optimized deposition parameters for Langmuir-Blodgett films suggest that the surface pressure is a key parameter to control the coverage of the film. The bulk concentration of nanosheets was found to be a less important deposition parameter in the LB deposition process. It only influenced whether the desired surface pressure could be reached at a given maximum degree of compression.

AB - The exfoliation and deposition of large (10–100 μm) Ti0.87O2 and small (0.1–1 μm) Ti0.91O2 nanosheets from lepidocrocite-type protonated titanates was investigated for getting high quality films. Exfoliation was carried out with different tetra-alkyl ammonium ions (TAA+) and varying TAA+/H+ ratios, and the colloidal solutions were characterized by small-angle X-ray scattering (SAXS) and ultraviolet–visible (UV–vis) spectroscopy. Using Langmuir-Blodgett deposition the titanate nanosheets were directly transferred onto a Si substrate. The resulting films were characterized by atomic force microscopy (AFM).The results indicate that the H1.07Ti1.73O4 titanate exfoliated at very low ratios of TAA+/H+; no lower threshold for exfoliation was observed for the TAA+ concentration. Nanosheets exfoliated at very low ratios of TAA+/H+ typically showed a small size and porous surface. Subsequent exfoliation of the remaining layered titanate particles yielded much higher quality nanosheets. The optimized deposition parameters for Langmuir-Blodgett films suggest that the surface pressure is a key parameter to control the coverage of the film. The bulk concentration of nanosheets was found to be a less important deposition parameter in the LB deposition process. It only influenced whether the desired surface pressure could be reached at a given maximum degree of compression.

KW - METIS-303774

KW - IR-94875

U2 - 10.1021/am501380d

DO - 10.1021/am501380d

M3 - Article

VL - 6

SP - 8567

EP - 8574

JO - ACS applied materials & interfaces

JF - ACS applied materials & interfaces

SN - 1944-8244

IS - 11

ER -