Improved rapid gas decompression of novel NBR-CTS polymer blends

Gina Butuc*, Kees van Leerdam, Brenda Rossenaar, Auke Talma, Anke Blume

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

Nitrile rubber (NBR) and polysulfides are two classes of polymers known for their resistance against swelling when in direct contact with hydrocarbon-based oils and non-polar solvents. In this study nitrile rubber (NBR) and a cyclic tetrasulfide (CTS) are combined with a goal of achieving a rubber blend that has superior properties than of each component. The role of CTS in the blend is discussed, as it presents several functions. This study represents a fundamental analysis of NBR-CTS blends, starting with polymeric phase analysis by Scanning Electron Microscopy (SEM) coupled with energy-dispersive X-ray spectroscopy (EDX). Thermodynamic compatibility studies are deployed in this study to illustrate the materials’ compatibility. Mechanical properties with an emphasis on Payne effect were also studied for blends of NBR-CTS. The synergistic effect found between NBR and CTS can be further expanded in a practical application of rapid gas decompression test as a side-by-side comparison for NBR and NBR-CTS blend compounds. This type of polymer blend represents a potential replacement of fluoroelastomers.

Original languageEnglish
Article number108502
JournalPolymer testing
Volume137
DOIs
Publication statusPublished - Aug 2024

Keywords

  • UT-Gold-D
  • Cyclic tetrasulfide
  • NBR
  • Rapid gas decompression
  • Rubber blend
  • Sulfur coagent
  • CTS

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