Increased hydrogen partial pressure suppresses and reverses hydrogen evolution during Pd catalysed electrolysis of CO2

M.J.W. Blom; W.P.M.  van Swaaij; G. Mul; S.R.A. Kersten

doi:10.1039/d0se00731e

Increased hydrogen partial pressure suppresses and reverses hydrogen evolution during Pd catalysed electrolysis of CO2

M.J.W. Blom
, W.P.M. van Swaaij
, G. Mul
, S.R.A. Kersten^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

4 Citations (Scopus)

151 Downloads (Pure)

Abstract

Electrochemical reduction of CO2 on a Pd/C cathode produces formate and hydrogen at low overpotentials. We report on an innovative, effective approach to prevent hydrogen formation. By applying 4 bar partial hydrogen pressure, hydrogen evolution can be fully avoided at −0.05 V vs. RHE and 1 bar partial CO2 pressure.

Original language	English
Pages (from-to)	4459-4463
Number of pages	5
Journal	Sustainable Energy & Fuels
Volume	4
Issue number	9
Early online date	30 Jun 2020
DOIs	https://doi.org/10.1039/d0se00731e
Publication status	Published - 1 Sept 2020

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy
SDG 13 Climate Action

Keywords

UT-Hybrid-D
Hydrogen evolution reaction
Electrochemical conversion
Renewable Energy
Energy storage technologies
Catalysis
Electrochemical CO reduction

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10.1039/d0se00731eLicence: CC BY-NC

ArticleFinal published version, 524 KBLicence: CC BY-NC

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abstract = "Electrochemical reduction of CO2 on a Pd/C cathode produces formate and hydrogen at low overpotentials. We report on an innovative, effective approach to prevent hydrogen formation. By applying 4 bar partial hydrogen pressure, hydrogen evolution can be fully avoided at −0.05 V vs. RHE and 1 bar partial CO2 pressure. ",

keywords = "UT-Hybrid-D, Hydrogen evolution reaction, Electrochemical conversion, Renewable Energy, Energy storage technologies, Catalysis, Electrochemical CO reduction",

author = "M.J.W. Blom and \{van Swaaij\}, W.P.M. and G. Mul and S.R.A. Kersten",

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AU - Blom, M.J.W.

AU - van Swaaij, W.P.M.

AU - Mul, G.

AU - Kersten, S.R.A.

N1 - RSC deal

PY - 2020/9/1

Y1 - 2020/9/1

N2 - Electrochemical reduction of CO2 on a Pd/C cathode produces formate and hydrogen at low overpotentials. We report on an innovative, effective approach to prevent hydrogen formation. By applying 4 bar partial hydrogen pressure, hydrogen evolution can be fully avoided at −0.05 V vs. RHE and 1 bar partial CO2 pressure.

AB - Electrochemical reduction of CO2 on a Pd/C cathode produces formate and hydrogen at low overpotentials. We report on an innovative, effective approach to prevent hydrogen formation. By applying 4 bar partial hydrogen pressure, hydrogen evolution can be fully avoided at −0.05 V vs. RHE and 1 bar partial CO2 pressure.

KW - UT-Hybrid-D

KW - Hydrogen evolution reaction

KW - Electrochemical conversion

KW - Renewable Energy

KW - Energy storage technologies

KW - Catalysis

KW - Electrochemical CO reduction

UR - https://www.scopus.com/pages/publications/85090090719

U2 - 10.1039/d0se00731e

DO - 10.1039/d0se00731e

M3 - Article

SN - 2398-4902

VL - 4

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EP - 4463

JO - Sustainable Energy & Fuels

JF - Sustainable Energy & Fuels

IS - 9

ER -

Increased hydrogen partial pressure suppresses and reverses hydrogen evolution during Pd catalysed electrolysis of CO2

Abstract

UN SDGs

Keywords

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