Increased luminescent lifetimes of Ln3+ complexes emitting in the near-infrared as a result of deuteration

G.A. Hebbink, David Reinhoudt, F.C.J.M. van Veggel

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    Abstract

    The luminescence of lanthanide(III) ions emitting in the near-infrared region is ideally suited for telecommunications applications, and a number of applications have been developed. These are in general based on inorganic matrices, but polymer-based matrices would have advantages in device fabrication. In organic matrices, however, molecular vibrations in the matrix quench the excited state of luminescent lanthanide ions. Replacement of strongly quenching groups such as C-H oscillators by more weakly quenching groups enhances the luminescence lifetime and hence also the luminescence quantum yield. This article reports a synthesis route developed in order to deuterate all C-H groups that contribute to the quenching in an organic lanthanide complex. The luminescences of three near-infrared emitting lanthanide ions - Nd3+, Er3+, and Yb3+ - were measured.
    Original languageUndefined
    Pages (from-to)4101-4106
    JournalEuropean journal of organic chemistry
    Volume2001
    Issue number21
    DOIs
    Publication statusPublished - 2001

    Keywords

    • METIS-202981
    • IR-36759

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