Influence of ionic conductivity of the nano-particulate coating phase on oxygen surface exchange of La0.58Sr0.4Co0.2Fe0.8O3-δ

S. Saher, S. Naqash, Bernard A. Boukamp, Bobing Hu, Changrong Xia, Henricus J.M. Bouwmeester

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

The oxygen surface exchange kinetics of mixed-conducting perovskite La0.58Sr0.4Co0.2Fe0.8O3 d (LSCF) ceramics coated with a porous nano-particulate layer of either gadolinea (Gd2O3), ceria (CeO2) or 20 mol% Gd-doped ceria (GCO) was determined by electrical conductivity relaxation (ECR). The measurements were performed in the temperature range 700–900 C, following pO2-step changes between 0.2 and 0.4 atm. The apparent value of the surface exchange coefficient, kchem, is found to vary with the loading amount and ionic conductivity of the coated phase whilst, as expected, the chemical diffusion coefficient Dchem remains invariant with the applied coating. Partial coverage of the LSCF surface with non-ionic conductive Gd2O3 or CeO2 lowers the value of kchem relative to that observed for bare LSCF, which is attributed to surface blocking effects. In contrast, partial coverage of LSCF with GCO electrolyte particles enhances the apparent value of kchem up to a factor of 6 compared to bare LSCF. The data of pulse isotope exchange (PIE) measurements show that the surface exchange reaction on bare LSCF is predominantly limited by dissociative adsorption of O2. Different mechanisms for the improved oxygen surface exchange kinetics after partially covering the LSCF surface with GCO are discussed.
Original languageEnglish
Pages (from-to)4991-4999
JournalJournal of materials chemistry. A
Volume5
Issue number10
DOIs
Publication statusPublished - 2017

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Ionic conductivity
Oxygen
Coatings
Cerium compounds
Kinetics
Isotopes
Perovskite
Electrolytes
Adsorption

Keywords

  • IR-104614
  • METIS-321848

Cite this

@article{17ac0a2a41e044ca96c44c112882cf41,
title = "Influence of ionic conductivity of the nano-particulate coating phase on oxygen surface exchange of La0.58Sr0.4Co0.2Fe0.8O3-δ",
abstract = "The oxygen surface exchange kinetics of mixed-conducting perovskite La0.58Sr0.4Co0.2Fe0.8O3 d (LSCF) ceramics coated with a porous nano-particulate layer of either gadolinea (Gd2O3), ceria (CeO2) or 20 mol{\%} Gd-doped ceria (GCO) was determined by electrical conductivity relaxation (ECR). The measurements were performed in the temperature range 700–900 C, following pO2-step changes between 0.2 and 0.4 atm. The apparent value of the surface exchange coefficient, kchem, is found to vary with the loading amount and ionic conductivity of the coated phase whilst, as expected, the chemical diffusion coefficient Dchem remains invariant with the applied coating. Partial coverage of the LSCF surface with non-ionic conductive Gd2O3 or CeO2 lowers the value of kchem relative to that observed for bare LSCF, which is attributed to surface blocking effects. In contrast, partial coverage of LSCF with GCO electrolyte particles enhances the apparent value of kchem up to a factor of 6 compared to bare LSCF. The data of pulse isotope exchange (PIE) measurements show that the surface exchange reaction on bare LSCF is predominantly limited by dissociative adsorption of O2. Different mechanisms for the improved oxygen surface exchange kinetics after partially covering the LSCF surface with GCO are discussed.",
keywords = "IR-104614, METIS-321848",
author = "S. Saher and S. Naqash and Boukamp, {Bernard A.} and Bobing Hu and Changrong Xia and Bouwmeester, {Henricus J.M.}",
year = "2017",
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language = "English",
volume = "5",
pages = "4991--4999",
journal = "Journal of materials chemistry. A",
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Influence of ionic conductivity of the nano-particulate coating phase on oxygen surface exchange of La0.58Sr0.4Co0.2Fe0.8O3-δ. / Saher, S.; Naqash, S.; Boukamp, Bernard A.; Hu, Bobing; Xia, Changrong; Bouwmeester, Henricus J.M.

In: Journal of materials chemistry. A, Vol. 5, No. 10, 2017, p. 4991-4999.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Influence of ionic conductivity of the nano-particulate coating phase on oxygen surface exchange of La0.58Sr0.4Co0.2Fe0.8O3-δ

AU - Saher, S.

AU - Naqash, S.

AU - Boukamp, Bernard A.

AU - Hu, Bobing

AU - Xia, Changrong

AU - Bouwmeester, Henricus J.M.

PY - 2017

Y1 - 2017

N2 - The oxygen surface exchange kinetics of mixed-conducting perovskite La0.58Sr0.4Co0.2Fe0.8O3 d (LSCF) ceramics coated with a porous nano-particulate layer of either gadolinea (Gd2O3), ceria (CeO2) or 20 mol% Gd-doped ceria (GCO) was determined by electrical conductivity relaxation (ECR). The measurements were performed in the temperature range 700–900 C, following pO2-step changes between 0.2 and 0.4 atm. The apparent value of the surface exchange coefficient, kchem, is found to vary with the loading amount and ionic conductivity of the coated phase whilst, as expected, the chemical diffusion coefficient Dchem remains invariant with the applied coating. Partial coverage of the LSCF surface with non-ionic conductive Gd2O3 or CeO2 lowers the value of kchem relative to that observed for bare LSCF, which is attributed to surface blocking effects. In contrast, partial coverage of LSCF with GCO electrolyte particles enhances the apparent value of kchem up to a factor of 6 compared to bare LSCF. The data of pulse isotope exchange (PIE) measurements show that the surface exchange reaction on bare LSCF is predominantly limited by dissociative adsorption of O2. Different mechanisms for the improved oxygen surface exchange kinetics after partially covering the LSCF surface with GCO are discussed.

AB - The oxygen surface exchange kinetics of mixed-conducting perovskite La0.58Sr0.4Co0.2Fe0.8O3 d (LSCF) ceramics coated with a porous nano-particulate layer of either gadolinea (Gd2O3), ceria (CeO2) or 20 mol% Gd-doped ceria (GCO) was determined by electrical conductivity relaxation (ECR). The measurements were performed in the temperature range 700–900 C, following pO2-step changes between 0.2 and 0.4 atm. The apparent value of the surface exchange coefficient, kchem, is found to vary with the loading amount and ionic conductivity of the coated phase whilst, as expected, the chemical diffusion coefficient Dchem remains invariant with the applied coating. Partial coverage of the LSCF surface with non-ionic conductive Gd2O3 or CeO2 lowers the value of kchem relative to that observed for bare LSCF, which is attributed to surface blocking effects. In contrast, partial coverage of LSCF with GCO electrolyte particles enhances the apparent value of kchem up to a factor of 6 compared to bare LSCF. The data of pulse isotope exchange (PIE) measurements show that the surface exchange reaction on bare LSCF is predominantly limited by dissociative adsorption of O2. Different mechanisms for the improved oxygen surface exchange kinetics after partially covering the LSCF surface with GCO are discussed.

KW - IR-104614

KW - METIS-321848

U2 - 10.1039/c6ta10954c

DO - 10.1039/c6ta10954c

M3 - Article

VL - 5

SP - 4991

EP - 4999

JO - Journal of materials chemistry. A

JF - Journal of materials chemistry. A

SN - 2050-7488

IS - 10

ER -