Influence of molecular length on the adsorption of linear trimethylsilylacetylene derivatives at the n-tetradecane/au(111) interface: chemisorption vs. physisorption

Aymeric Nion, Nathalie Hélène Katsonis, Alexandre Marchenko, Corinne Aubert, Denis Fichou

Research output: Contribution to journalArticleAcademicpeer-review

10 Citations (Scopus)

Abstract

Adsorption of two trimethylsilylacetylene (TMSA) derivatives bearing linear alkyl chains of different lengths has been studied at the n-tetradecane/Au(111) interface. The lying or standing orientation of TMSA compounds on the gold surface shows that adsorption is not only controlled by the chemical reactivity of the molecules but also by their size.
Original languageEnglish
Pages (from-to)2261-2265
Number of pages4
JournalNew journal of chemistry
Volume37
DOIs
Publication statusPublished - 2013

Keywords

  • METIS-301663
  • IR-90143

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