Influence of pressure on diels-alder reactions performed in glass microreactors

F. Benito-López; R.M. Tiggelaar; A.J. Kettelarij; R.J.M. Egberink; J. G.E. Gardeniers; D.N. Reinhoudt; W. Verboom

Influence of pressure on diels-alder reactions performed in glass microreactors

F. Benito-López, R.M. Tiggelaar, A.J. Kettelarij, R.J.M. Egberink, J. G.E. Gardeniers, D.N. Reinhoudt, W. Verboom

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

Abstract

A microreactor platform that resists pressures up to 150 bar has been constructed and used to study the influence of pressure on the Diels-Alder reaction of cyclopentadiene with methyl-, phenyl- and benzylmaleimides. The reaction of cyclopentadiene with phenylmaleimide and benzylmaleimide showed 1.7-fold and 1.3-fold higher conversions, respectively, compared with batch experiments, whereas the reaction of cyclopentadiene with methylmaleimide was alsmost not accelerated.

Original language	English
Title of host publication	Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007
Editors	Jean-Louis Viovy, Patrick Tabeling, Stephanie Descroix, Laurent Malaquin
Publisher	The Chemical and Biological Microsystems Society
Pages	264-266
Number of pages	3
ISBN (Electronic)	9780979806407
Publication status	Published - 2007
Event	11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, µTAS 2007 - Paris, France Duration: 7 Oct 2007 → 11 Oct 2007 Conference number: 11

Conference

Conference	11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, µTAS 2007
Abbreviated title	MicroTAS
Country/Territory	France
City	Paris
Period	7/10/07 → 11/10/07

Keywords

Diels-Alder
Glass microreactor
High-pressure
Rate enhancements

Cite this

Benito-López, F., Tiggelaar, R. M., Kettelarij, A. J., Egberink, R. J. M., Gardeniers, J. G. E., Reinhoudt, D. N., & Verboom, W. (2007). Influence of pressure on diels-alder reactions performed in glass microreactors. In J.-L. Viovy, P. Tabeling, S. Descroix, & L. Malaquin (Eds.), Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007 (pp. 264-266). The Chemical and Biological Microsystems Society.

Benito-López, F. ; Tiggelaar, R.M. ; Kettelarij, A.J. et al. / Influence of pressure on diels-alder reactions performed in glass microreactors. Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007. editor / Jean-Louis Viovy ; Patrick Tabeling ; Stephanie Descroix ; Laurent Malaquin. The Chemical and Biological Microsystems Society, 2007. pp. 264-266

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title = "Influence of pressure on diels-alder reactions performed in glass microreactors",

abstract = "A microreactor platform that resists pressures up to 150 bar has been constructed and used to study the influence of pressure on the Diels-Alder reaction of cyclopentadiene with methyl-, phenyl- and benzylmaleimides. The reaction of cyclopentadiene with phenylmaleimide and benzylmaleimide showed 1.7-fold and 1.3-fold higher conversions, respectively, compared with batch experiments, whereas the reaction of cyclopentadiene with methylmaleimide was alsmost not accelerated.",

keywords = "Diels-Alder, Glass microreactor, High-pressure, Rate enhancements",

author = "F. Benito-L{\'o}pez and R.M. Tiggelaar and A.J. Kettelarij and R.J.M. Egberink and Gardeniers, {J. G.E.} and D.N. Reinhoudt and W. Verboom",

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year = "2007",

language = "English",

pages = "264--266",

editor = "Jean-Louis Viovy and Patrick Tabeling and Stephanie Descroix and Laurent Malaquin",

booktitle = "Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007",

publisher = "The Chemical and Biological Microsystems Society",

}

Benito-López, F, Tiggelaar, RM, Kettelarij, AJ, Egberink, RJM , Gardeniers, JGE , Reinhoudt, DN & Verboom, W 2007, Influence of pressure on diels-alder reactions performed in glass microreactors. in J-L Viovy, P Tabeling, S Descroix & L Malaquin (eds), Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007. The Chemical and Biological Microsystems Society, pp. 264-266, 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, µTAS 2007, Paris, France, 7/10/07.

Influence of pressure on diels-alder reactions performed in glass microreactors. / Benito-López, F.; Tiggelaar, R.M.; Kettelarij, A.J. et al.
Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007. ed. / Jean-Louis Viovy; Patrick Tabeling; Stephanie Descroix; Laurent Malaquin. The Chemical and Biological Microsystems Society, 2007. p. 264-266.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic › peer-review

TY - GEN

T1 - Influence of pressure on diels-alder reactions performed in glass microreactors

AU - Benito-López, F.

AU - Tiggelaar, R.M.

AU - Kettelarij, A.J.

AU - Egberink, R.J.M.

AU - Gardeniers, J. G.E.

AU - Reinhoudt, D.N.

AU - Verboom, W.

N1 - Conference code: 11

PY - 2007

Y1 - 2007

N2 - A microreactor platform that resists pressures up to 150 bar has been constructed and used to study the influence of pressure on the Diels-Alder reaction of cyclopentadiene with methyl-, phenyl- and benzylmaleimides. The reaction of cyclopentadiene with phenylmaleimide and benzylmaleimide showed 1.7-fold and 1.3-fold higher conversions, respectively, compared with batch experiments, whereas the reaction of cyclopentadiene with methylmaleimide was alsmost not accelerated.

AB - A microreactor platform that resists pressures up to 150 bar has been constructed and used to study the influence of pressure on the Diels-Alder reaction of cyclopentadiene with methyl-, phenyl- and benzylmaleimides. The reaction of cyclopentadiene with phenylmaleimide and benzylmaleimide showed 1.7-fold and 1.3-fold higher conversions, respectively, compared with batch experiments, whereas the reaction of cyclopentadiene with methylmaleimide was alsmost not accelerated.

KW - Diels-Alder

KW - Glass microreactor

KW - High-pressure

KW - Rate enhancements

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EP - 266

BT - Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007

A2 - Viovy, Jean-Louis

A2 - Tabeling, Patrick

A2 - Descroix, Stephanie

A2 - Malaquin, Laurent

PB - The Chemical and Biological Microsystems Society

T2 - 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, µTAS 2007

Y2 - 7 October 2007 through 11 October 2007

ER -

Benito-López F, Tiggelaar RM, Kettelarij AJ, Egberink RJM , Gardeniers JGE , Reinhoudt DN et al. Influence of pressure on diels-alder reactions performed in glass microreactors. In Viovy JL, Tabeling P, Descroix S, Malaquin L, editors, Proceedings of the 11th International Conference on Miniaturized Systems for Chemistry and Life Sciences, uTAS 2007. The Chemical and Biological Microsystems Society. 2007. p. 264-266

Influence of pressure on diels-alder reactions performed in glass microreactors

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