Initial Steps toward the Development of Grafted Ionic Liquid Membranes for the Selective Transport of CO2

Marie Alix Pizzoccaro-Zilamy; Martin Drobek; Eddy Petit; Cédric Totée; Gilles Silly; Gilles Guerrero; Matthew G. Cowan; André Ayral; Anne Julbe

doi:10.1021/acs.iecr.8b02466

Initial Steps toward the Development of Grafted Ionic Liquid Membranes for the Selective Transport of CO₂

Marie Alix Pizzoccaro-Zilamy, Martin Drobek, Eddy Petit, Cédric Totée, Gilles Silly, Gilles Guerrero, Matthew G. Cowan, André Ayral, Anne Julbe^*

^*Corresponding author for this work

Inorganic Membranes

Research output: Contribution to journal › Special issue › Academic › peer-review

12 Citations (Scopus)

13 Downloads (Pure)

Abstract

This work reports on a promising strategy for the development of novel grafted ionic liquid membranes (GILMs) in which phosphonate-based ILs are confined within the pores of a mesoporous γ-Al₂O₃ ceramic membrane by chemical grafting. The effect of both the chemical nature (i.e., alkyl versus ether) of the organic spacer chain and the presence of phosphonate coupling functions were evidenced as crucial parameters influencing CO₂ transport through the membranes. The effectiveness of the grafting procedure yielding GILMs was clearly demonstrated by Fourier transform infrared spectroscopy and high resolution-magic angle spinning NMR, and attractive membrane performance was evidenced through both the CO₂/N₂ ideal selectivity (∼140) and CO₂ permeability (∼130 Barrer).

Original language	English
Pages (from-to)	16027-16040
Number of pages	14
Journal	Industrial & engineering chemistry research
Volume	57
Issue number	47
DOIs	https://doi.org/10.1021/acs.iecr.8b02466
Publication status	Published - 19 Sep 2018

Keywords

UT-Hybrid-D
22/4 OA procedure

Access to Document

10.1021/acs.iecr.8b02466

acs.iecr.8b02466Final published version, 10.2 MBLicence: Taverne
Initial Steps toward the Development of Grafted Ionic Liquid Membranes for the Selective Transport of CO2. Final published version, 10.2 MBLicence: Taverne

Cite this

@article{2a4f4c9a040a4cdfb3ba2e860ad71b5a,

title = "Initial Steps toward the Development of Grafted Ionic Liquid Membranes for the Selective Transport of CO2",

abstract = "This work reports on a promising strategy for the development of novel grafted ionic liquid membranes (GILMs) in which phosphonate-based ILs are confined within the pores of a mesoporous γ-Al2O3 ceramic membrane by chemical grafting. The effect of both the chemical nature (i.e., alkyl versus ether) of the organic spacer chain and the presence of phosphonate coupling functions were evidenced as crucial parameters influencing CO2 transport through the membranes. The effectiveness of the grafting procedure yielding GILMs was clearly demonstrated by Fourier transform infrared spectroscopy and high resolution-magic angle spinning NMR, and attractive membrane performance was evidenced through both the CO2/N2 ideal selectivity (∼140) and CO2 permeability (∼130 Barrer).",

keywords = "UT-Hybrid-D, 22/4 OA procedure",

author = "Pizzoccaro-Zilamy, {Marie Alix} and Martin Drobek and Eddy Petit and C{\'e}dric Tot{\'e}e and Gilles Silly and Gilles Guerrero and Cowan, {Matthew G.} and Andr{\'e} Ayral and Anne Julbe",

note = "ACS deal",

year = "2018",

month = sep,

day = "19",

doi = "10.1021/acs.iecr.8b02466",

language = "English",

volume = "57",

pages = "16027--16040",

journal = "Industrial & engineering chemistry research",

issn = "0888-5885",

publisher = "American Chemical Society",

number = "47",

}

TY - JOUR

T1 - Initial Steps toward the Development of Grafted Ionic Liquid Membranes for the Selective Transport of CO2

AU - Pizzoccaro-Zilamy, Marie Alix

AU - Drobek, Martin

AU - Petit, Eddy

AU - Totée, Cédric

AU - Silly, Gilles

AU - Guerrero, Gilles

AU - Cowan, Matthew G.

AU - Ayral, André

AU - Julbe, Anne

N1 - ACS deal

PY - 2018/9/19

Y1 - 2018/9/19

N2 - This work reports on a promising strategy for the development of novel grafted ionic liquid membranes (GILMs) in which phosphonate-based ILs are confined within the pores of a mesoporous γ-Al2O3 ceramic membrane by chemical grafting. The effect of both the chemical nature (i.e., alkyl versus ether) of the organic spacer chain and the presence of phosphonate coupling functions were evidenced as crucial parameters influencing CO2 transport through the membranes. The effectiveness of the grafting procedure yielding GILMs was clearly demonstrated by Fourier transform infrared spectroscopy and high resolution-magic angle spinning NMR, and attractive membrane performance was evidenced through both the CO2/N2 ideal selectivity (∼140) and CO2 permeability (∼130 Barrer).

AB - This work reports on a promising strategy for the development of novel grafted ionic liquid membranes (GILMs) in which phosphonate-based ILs are confined within the pores of a mesoporous γ-Al2O3 ceramic membrane by chemical grafting. The effect of both the chemical nature (i.e., alkyl versus ether) of the organic spacer chain and the presence of phosphonate coupling functions were evidenced as crucial parameters influencing CO2 transport through the membranes. The effectiveness of the grafting procedure yielding GILMs was clearly demonstrated by Fourier transform infrared spectroscopy and high resolution-magic angle spinning NMR, and attractive membrane performance was evidenced through both the CO2/N2 ideal selectivity (∼140) and CO2 permeability (∼130 Barrer).

KW - UT-Hybrid-D

KW - 22/4 OA procedure

UR - http://www.scopus.com/inward/record.url?scp=85054849198&partnerID=8YFLogxK

U2 - 10.1021/acs.iecr.8b02466

DO - 10.1021/acs.iecr.8b02466

M3 - Special issue

AN - SCOPUS:85054849198

VL - 57

SP - 16027

EP - 16040

JO - Industrial & engineering chemistry research

JF - Industrial & engineering chemistry research

SN - 0888-5885

IS - 47

ER -

Initial Steps toward the Development of Grafted Ionic Liquid Membranes for the Selective Transport of CO₂

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this