Interpretation of an 'inductive loop' in the impedance of an oxygen ion conducting electrolyte/metal electrode system

Bernard A. Boukamp

doi:10.1016/S0167-2738(01)00832-3

Interpretation of an 'inductive loop' in the impedance of an oxygen ion conducting electrolyte/metal electrode system

Bernard A. Boukamp

Inorganic Materials Science

Research output: Contribution to journal › Article › Academic › peer-review

42 Citations (Scopus)

10 Downloads (Pure)

Abstract

CNLS-fit analysis of the electrode impedance of two different oxygen ion conducting electrolytes showed the presence of a small but significant ‘inductive loop’ at low frequencies and at zero bias. This phenomenon is explained by a ‘crosstalk’ between the working electrode and the reference electrode. It is assumed that mobile and possibly charged, adsorbed oxygen species mediate this crosstalk. Based on this, a simple model is derived which will lead, in first approximation, to an ‘inductive loop’ in the impedance diagram of the electrode response.

Original language	Undefined
Pages (from-to)	47-55
Number of pages	9
Journal	Solid state ionics
Volume	143
Issue number	1
DOIs	https://doi.org/10.1016/S0167-2738(01)00832-3
Publication status	Published - 2001

Keywords

Electrochemical impedance spectroscopy (EIS)
Oxygen electrodes
METIS-203047
IR-74473
Inductive loop
Oxygen ion conducting ceramics

Access to Document

10.1016/S0167-2738(01)00832-3

Cite this

@article{d704acd97d074e9a8595fb2b53ae3bef,

title = "Interpretation of an 'inductive loop' in the impedance of an oxygen ion conducting electrolyte/metal electrode system",

abstract = "CNLS-fit analysis of the electrode impedance of two different oxygen ion conducting electrolytes showed the presence of a small but significant {\textquoteleft}inductive loop{\textquoteright} at low frequencies and at zero bias. This phenomenon is explained by a {\textquoteleft}crosstalk{\textquoteright} between the working electrode and the reference electrode. It is assumed that mobile and possibly charged, adsorbed oxygen species mediate this crosstalk. Based on this, a simple model is derived which will lead, in first approximation, to an {\textquoteleft}inductive loop{\textquoteright} in the impedance diagram of the electrode response.",

keywords = "Electrochemical impedance spectroscopy (EIS), Oxygen electrodes, METIS-203047, IR-74473, Inductive loop, Oxygen ion conducting ceramics",

author = "Boukamp, {Bernard A.}",

year = "2001",

doi = "10.1016/S0167-2738(01)00832-3",

language = "Undefined",

volume = "143",

pages = "47--55",

journal = "Solid state ionics",

issn = "0167-2738",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Interpretation of an 'inductive loop' in the impedance of an oxygen ion conducting electrolyte/metal electrode system

AU - Boukamp, Bernard A.

PY - 2001

Y1 - 2001

N2 - CNLS-fit analysis of the electrode impedance of two different oxygen ion conducting electrolytes showed the presence of a small but significant ‘inductive loop’ at low frequencies and at zero bias. This phenomenon is explained by a ‘crosstalk’ between the working electrode and the reference electrode. It is assumed that mobile and possibly charged, adsorbed oxygen species mediate this crosstalk. Based on this, a simple model is derived which will lead, in first approximation, to an ‘inductive loop’ in the impedance diagram of the electrode response.

AB - CNLS-fit analysis of the electrode impedance of two different oxygen ion conducting electrolytes showed the presence of a small but significant ‘inductive loop’ at low frequencies and at zero bias. This phenomenon is explained by a ‘crosstalk’ between the working electrode and the reference electrode. It is assumed that mobile and possibly charged, adsorbed oxygen species mediate this crosstalk. Based on this, a simple model is derived which will lead, in first approximation, to an ‘inductive loop’ in the impedance diagram of the electrode response.

KW - Electrochemical impedance spectroscopy (EIS)

KW - Oxygen electrodes

KW - METIS-203047

KW - IR-74473

KW - Inductive loop

KW - Oxygen ion conducting ceramics

U2 - 10.1016/S0167-2738(01)00832-3

DO - 10.1016/S0167-2738(01)00832-3

M3 - Article

SN - 0167-2738

VL - 143

SP - 47

EP - 55

JO - Solid state ionics

JF - Solid state ionics

IS - 1

ER -