Isobaric low-pressure vapor-liquid equilibrium data of the system monochloroacetic acid+dichloroacetic acid+diethylene glycol dipentyl ether and the constituent binary systems

Mark Jongmans; A. Londono; Boelo Schuur; A.B. de Haan

doi:10.1016/j.fluid.2012.07.027

Isobaric low-pressure vapor-liquid equilibrium data of the system monochloroacetic acid+dichloroacetic acid+diethylene glycol dipentyl ether and the constituent binary systems

Mark Jongmans, A. Londono, Boelo Schuur, A.B. de Haan

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Abstract

In this study, binary and ternary VLE data have been determined at 5, 7.5, and 10 kPa for the system monochloracetic acid (MCA) + dichloroacetic acid (DCA) + diethylene glycol dipentyl ether (DGDP). The extractant DGDP enhances the relative volatility of the MCA/DCA system from 1.2 without extractant up to 4. The non-ideal behavior in the liquid and vapor phase was reasonably well correlated with the NRTL and Hayden–O’Connell (HOC) model, respectively. The binary and ternary VLE data were correlated separately to obtain a better description of both datasets

Original language	English
Pages (from-to)	15-21
Number of pages	7
Journal	Fluid phase equilibria
Volume	334
DOIs	https://doi.org/10.1016/j.fluid.2012.07.027
Publication status	Published - 2012

Keywords

IR-81926
METIS-288582

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10.1016/j.fluid.2012.07.027

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title = "Isobaric low-pressure vapor-liquid equilibrium data of the system monochloroacetic acid+dichloroacetic acid+diethylene glycol dipentyl ether and the constituent binary systems",

abstract = "In this study, binary and ternary VLE data have been determined at 5, 7.5, and 10 kPa for the system monochloracetic acid (MCA) + dichloroacetic acid (DCA) + diethylene glycol dipentyl ether (DGDP). The extractant DGDP enhances the relative volatility of the MCA/DCA system from 1.2 without extractant up to 4. The non-ideal behavior in the liquid and vapor phase was reasonably well correlated with the NRTL and Hayden–O{\textquoteright}Connell (HOC) model, respectively. The binary and ternary VLE data were correlated separately to obtain a better description of both datasets",

keywords = "IR-81926, METIS-288582",

author = "Mark Jongmans and A. Londono and Boelo Schuur and {de Haan}, A.B.",

year = "2012",

doi = "10.1016/j.fluid.2012.07.027",

language = "English",

volume = "334",

pages = "15--21",

journal = "Fluid phase equilibria",

issn = "0378-3812",

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T1 - Isobaric low-pressure vapor-liquid equilibrium data of the system monochloroacetic acid+dichloroacetic acid+diethylene glycol dipentyl ether and the constituent binary systems

AU - Jongmans, Mark

AU - Londono, A.

AU - Schuur, Boelo

AU - de Haan, A.B.

PY - 2012

Y1 - 2012

N2 - In this study, binary and ternary VLE data have been determined at 5, 7.5, and 10 kPa for the system monochloracetic acid (MCA) + dichloroacetic acid (DCA) + diethylene glycol dipentyl ether (DGDP). The extractant DGDP enhances the relative volatility of the MCA/DCA system from 1.2 without extractant up to 4. The non-ideal behavior in the liquid and vapor phase was reasonably well correlated with the NRTL and Hayden–O’Connell (HOC) model, respectively. The binary and ternary VLE data were correlated separately to obtain a better description of both datasets

AB - In this study, binary and ternary VLE data have been determined at 5, 7.5, and 10 kPa for the system monochloracetic acid (MCA) + dichloroacetic acid (DCA) + diethylene glycol dipentyl ether (DGDP). The extractant DGDP enhances the relative volatility of the MCA/DCA system from 1.2 without extractant up to 4. The non-ideal behavior in the liquid and vapor phase was reasonably well correlated with the NRTL and Hayden–O’Connell (HOC) model, respectively. The binary and ternary VLE data were correlated separately to obtain a better description of both datasets

KW - IR-81926

KW - METIS-288582

U2 - 10.1016/j.fluid.2012.07.027

DO - 10.1016/j.fluid.2012.07.027

M3 - Article

SN - 0378-3812

VL - 334

SP - 15

EP - 21

JO - Fluid phase equilibria

JF - Fluid phase equilibria

ER -

Isobaric low-pressure vapor-liquid equilibrium data of the system monochloroacetic acid+dichloroacetic acid+diethylene glycol dipentyl ether and the constituent binary systems

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Keywords

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