Jahn-teller distortions in copper(II) complexes as determined from ESR powder spectra

B. Nieuwenhuijse, J. Reedijk

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Abstract

Cations Cu(ligand)2+6 doped in lattices of non-cubic Zn(ligand)6(anion)2 are shown to have ESR powder spectra, corresponding with two types of cations, distorted octahedral and regular octahedral. Upon lowering of the temperature the number of distorted molecules increases. Despite of the non-cubic symmetry the results are essentially similar to single crystal observations and investigations on cubic lattices.
Original languageEnglish
Pages (from-to)201-203
JournalChemical physics letters
Volume22
Issue number1
DOIs
Publication statusPublished - 1973
Externally publishedYes

Fingerprint

Jahn-Teller effect
Powders
Paramagnetic resonance
Cations
Copper
Ligands
cations
copper
ligands
Crystal symmetry
cubic lattices
Crystal lattices
Anions
Single crystals
anions
Molecules
single crystals
symmetry
molecules
Temperature

Keywords

  • IR-68181

Cite this

Nieuwenhuijse, B. ; Reedijk, J. / Jahn-teller distortions in copper(II) complexes as determined from ESR powder spectra. In: Chemical physics letters. 1973 ; Vol. 22, No. 1. pp. 201-203.
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Jahn-teller distortions in copper(II) complexes as determined from ESR powder spectra. / Nieuwenhuijse, B.; Reedijk, J.

In: Chemical physics letters, Vol. 22, No. 1, 1973, p. 201-203.

Research output: Contribution to journalArticleAcademicpeer-review

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T1 - Jahn-teller distortions in copper(II) complexes as determined from ESR powder spectra

AU - Nieuwenhuijse, B.

AU - Reedijk, J.

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N2 - Cations Cu(ligand)2+6 doped in lattices of non-cubic Zn(ligand)6(anion)2 are shown to have ESR powder spectra, corresponding with two types of cations, distorted octahedral and regular octahedral. Upon lowering of the temperature the number of distorted molecules increases. Despite of the non-cubic symmetry the results are essentially similar to single crystal observations and investigations on cubic lattices.

AB - Cations Cu(ligand)2+6 doped in lattices of non-cubic Zn(ligand)6(anion)2 are shown to have ESR powder spectra, corresponding with two types of cations, distorted octahedral and regular octahedral. Upon lowering of the temperature the number of distorted molecules increases. Despite of the non-cubic symmetry the results are essentially similar to single crystal observations and investigations on cubic lattices.

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DO - 10.1016/0009-2614(73)80570-6

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