Li intercalation into multilayer graphene with controlled defect densities

Michal W. Ochapski; Derya  Ataç; Johnny G.M. Sanderink; Alexey Y. Kovalgin; Michel P. de Jong

doi:10.1016/j.cartre.2021.100045

Li intercalation into multilayer graphene with controlled defect densities

Michal W. Ochapski^*, Derya Ataç, Johnny G.M. Sanderink, Alexey Y. Kovalgin, Michel P. de Jong

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

8 Citations (Scopus)

121 Downloads (Pure)

Abstract

We studied the influence of defect density in multilayer graphene sheets on the intercalation of Li ions by means of x-ray photoelectron spectroscopy. The multilayer graphene was prepared by chemical vapor deposition on Ni substrates. The deposition of Li at room temperature results in immediate intercalation, while additional annealing at 300 °C partially removes Li from the sample surface. We found that varying the defect density over several orders of magnitude does not influence the intercalation process. We propose that the edges of the graphene flakes are the dominant sites that facilitate Li intercalation in multilayer graphene.

Original language	English
Article number	100045
Number of pages	6
Journal	Carbon trends
Volume	4
Early online date	20 Mar 2021
DOIs	https://doi.org/10.1016/j.cartre.2021.100045
Publication status	Published - 4 Jul 2021

Keywords

UT-Gold-D

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.cartre.2021.100045Licence: CC BY

ArticleFinal published version, 1.14 MBLicence: CC BY

Cite this

@article{8735ce51e7aa451f9e3abbb49a6aea31,

title = "Li intercalation into multilayer graphene with controlled defect densities",

abstract = "We studied the influence of defect density in multilayer graphene sheets on the intercalation of Li ions by means of x-ray photoelectron spectroscopy. The multilayer graphene was prepared by chemical vapor deposition on Ni substrates. The deposition of Li at room temperature results in immediate intercalation, while additional annealing at 300 °C partially removes Li from the sample surface. We found that varying the defect density over several orders of magnitude does not influence the intercalation process. We propose that the edges of the graphene flakes are the dominant sites that facilitate Li intercalation in multilayer graphene.",

keywords = "UT-Gold-D",

author = "Ochapski, {Michal W.} and Derya Ata{\c c} and Sanderink, {Johnny G.M.} and Kovalgin, {Alexey Y.} and {de Jong}, {Michel P.}",

year = "2021",

month = jul,

day = "4",

doi = "10.1016/j.cartre.2021.100045",

language = "English",

volume = "4",

journal = "Carbon trends",

issn = "2667-0569",

publisher = "Elsevier",

}

TY - JOUR

T1 - Li intercalation into multilayer graphene with controlled defect densities

AU - Ochapski, Michal W.

AU - Ataç, Derya

AU - Sanderink, Johnny G.M.

AU - Kovalgin, Alexey Y.

AU - de Jong, Michel P.

PY - 2021/7/4

Y1 - 2021/7/4

N2 - We studied the influence of defect density in multilayer graphene sheets on the intercalation of Li ions by means of x-ray photoelectron spectroscopy. The multilayer graphene was prepared by chemical vapor deposition on Ni substrates. The deposition of Li at room temperature results in immediate intercalation, while additional annealing at 300 °C partially removes Li from the sample surface. We found that varying the defect density over several orders of magnitude does not influence the intercalation process. We propose that the edges of the graphene flakes are the dominant sites that facilitate Li intercalation in multilayer graphene.

AB - We studied the influence of defect density in multilayer graphene sheets on the intercalation of Li ions by means of x-ray photoelectron spectroscopy. The multilayer graphene was prepared by chemical vapor deposition on Ni substrates. The deposition of Li at room temperature results in immediate intercalation, while additional annealing at 300 °C partially removes Li from the sample surface. We found that varying the defect density over several orders of magnitude does not influence the intercalation process. We propose that the edges of the graphene flakes are the dominant sites that facilitate Li intercalation in multilayer graphene.

KW - UT-Gold-D

U2 - 10.1016/j.cartre.2021.100045

DO - 10.1016/j.cartre.2021.100045

M3 - Article

SN - 2667-0569

VL - 4

JO - Carbon trends

JF - Carbon trends

M1 - 100045

ER -

Li intercalation into multilayer graphene with controlled defect densities

Abstract

Keywords

UN SDGs

Access to Document

Fingerprint

Cite this