Living anionic polymerization of functional aziridines

Laura Thomi; Frederik R. Wurm

doi:10.1002/masy.201400006

Living anionic polymerization of functional aziridines

Laura Thomi
, Frederik R. Wurm^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

21 Citations (Scopus)

Abstract

Summary 2-(Oct-7-en-1-yl)-N-mesylaziridine was used as a novel monomer for the anionic ring-opening polymerization. This is the first functional aziridine-derivative that can be polymerized via an anionic mechanism. Homo- and copolymers with (2-n-decyl-N-mesylaziridine) were synthesized and characterized via NMR spectroscopy and SEC. Molecular weight distributions were all monomodal and very narrow (M_w/M_n < 1.1). The pendant double bonds were functionalized with a protected cysteine derivative as a model for potential bioconjugation.

Original language	English
Pages (from-to)	51-56
Number of pages	6
Journal	Macromolecular symposia
Volume	349
Issue number	1
DOIs	https://doi.org/10.1002/masy.201400006
Publication status	Published - 1 Mar 2015
Externally published	Yes

Keywords

anionic polymerization
aziridine
polyamine
ring-opening polymerization
thiol-ene reaction

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10.1002/masy.201400006

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abstract = "Summary 2-(Oct-7-en-1-yl)-N-mesylaziridine was used as a novel monomer for the anionic ring-opening polymerization. This is the first functional aziridine-derivative that can be polymerized via an anionic mechanism. Homo- and copolymers with (2-n-decyl-N-mesylaziridine) were synthesized and characterized via NMR spectroscopy and SEC. Molecular weight distributions were all monomodal and very narrow (Mw/Mn < 1.1). The pendant double bonds were functionalized with a protected cysteine derivative as a model for potential bioconjugation.",

keywords = "anionic polymerization, aziridine, polyamine, ring-opening polymerization, thiol-ene reaction",

author = "Laura Thomi and Wurm, \{Frederik R.\}",

year = "2015",

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doi = "10.1002/masy.201400006",

language = "English",

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journal = "Macromolecular symposia",

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AU - Thomi, Laura

AU - Wurm, Frederik R.

PY - 2015/3/1

Y1 - 2015/3/1

N2 - Summary 2-(Oct-7-en-1-yl)-N-mesylaziridine was used as a novel monomer for the anionic ring-opening polymerization. This is the first functional aziridine-derivative that can be polymerized via an anionic mechanism. Homo- and copolymers with (2-n-decyl-N-mesylaziridine) were synthesized and characterized via NMR spectroscopy and SEC. Molecular weight distributions were all monomodal and very narrow (Mw/Mn < 1.1). The pendant double bonds were functionalized with a protected cysteine derivative as a model for potential bioconjugation.

AB - Summary 2-(Oct-7-en-1-yl)-N-mesylaziridine was used as a novel monomer for the anionic ring-opening polymerization. This is the first functional aziridine-derivative that can be polymerized via an anionic mechanism. Homo- and copolymers with (2-n-decyl-N-mesylaziridine) were synthesized and characterized via NMR spectroscopy and SEC. Molecular weight distributions were all monomodal and very narrow (Mw/Mn < 1.1). The pendant double bonds were functionalized with a protected cysteine derivative as a model for potential bioconjugation.

KW - anionic polymerization

KW - aziridine

KW - polyamine

KW - ring-opening polymerization

KW - thiol-ene reaction

UR - https://www.scopus.com/pages/publications/84925637181

U2 - 10.1002/masy.201400006

DO - 10.1002/masy.201400006

M3 - Article

AN - SCOPUS:84925637181

SN - 1022-1360

VL - 349

SP - 51

EP - 56

JO - Macromolecular symposia

JF - Macromolecular symposia

IS - 1

ER -

Living anionic polymerization of functional aziridines

Abstract

Keywords

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