Long-chain branched ROMP polymers

Stefan Hilf; Frederik Wurm; Andreas F.M. Kilbinger

doi:10.1002/pola.23733

Long-chain branched ROMP polymers

Stefan Hilf, Frederik Wurm, Andreas F.M. Kilbinger

Research output: Contribution to journal › Article › Academic › peer-review

17 Citations (Scopus)

Abstract

This article describes the construction of branched ROMP-polymer architectures via polycondensation of AB_n-type macromonomers. For this convergent strategy, a polymer was synthesized that carries several hydroxyl-groups along the polymer chain and one carboxylic acid group at the chain end. An esterification reaction between these functional groups yielded long-chain branched polymers. The polymers were analyzed by NMR and SEC to monitor the condensation reaction.

Original language	English
Pages (from-to)	6932-6940
Number of pages	9
Journal	Journal of polymer science. Part A: Polymer chemistry
Volume	47
Issue number	24
DOIs	https://doi.org/10.1002/pola.23733
Publication status	Published - 15 Dec 2009
Externally published	Yes

Keywords

Branched polymers
Functionalization of polymers
Hypermacs
Macromonomers
ROMP

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10.1002/pola.23733

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KW - Functionalization of polymers

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KW - Macromonomers

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Long-chain branched ROMP polymers

Abstract

Keywords

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