Low-Temperature High-Mobility Amorphous IZO for Silicon Heterojunction Solar Cells

Monica Morales-Masis, Silvia Martin De Nicolas, Jakub Holovský, Stefaan De Wolf, Christophe Ballif

Research output: Contribution to journalArticleAcademicpeer-review

64 Citations (Scopus)

Abstract

Parasitic absorption in the transparent conductive oxide (TCO) front electrode is one of the limitations of silicon heterojunction (SHJ) solar cells efficiency. To avoid such absorption while retaining high conductivity, TCOs with high electron mobility are preferred over those with high carrier density. Here, we demonstrate improved SHJ solar cell efficiencies by applying high-mobility amorphous indium zinc oxide (a-IZO) as the front TCO. We sputtered a-IZO at low substrate temperature and low power density and investigated the optical and electrical properties, as well as subband tail formation-quantified by the Urbach energy (EU )-as a function of the sputtering oxygen partial pressure. We obtain anEU as low as 128 meV for films with the highest Hall mobility of 60 cm2/V • s. When comparing the performance of a-IZO films with indium tin oxide (ITO) and hydrogenated indium oxide (IO:H), we find that IO:H (115 cm2/V • s) exhibits a similar EU of 130 meV, while ITO (25 cm2/V•s) presents a much larger EU of up to 270 meV. The high film quality, indicated by the low EU , the high mobility, and low free carrier absorption of the developed a-IZO electrodes, result in a significant current improvement, achieving conversion efficiencies over 21.5%, outperforming those with standard ITO.

Original languageEnglish
Article number7155475
Pages (from-to)1340-1347
Number of pages8
JournalIEEE journal of photovoltaics
Volume5
Issue number5
DOIs
Publication statusPublished - 1 Sep 2015
Externally publishedYes

Keywords

  • Amorphous indium zinc oxide
  • Electron mobility
  • Heterojunction
  • Indium tin oxide (ITO)
  • Silicon
  • Solar cells
  • Transparent conductive oxides (TCOs)
  • Urbach energy

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