TY - JOUR
T1 - Magnetic properties of ammonia intercalates of some IV B and V B transition metal disulfides
AU - Bouwmeester, H. J.M.
AU - Wiegers, G. A.
AU - van Bruggen, C. F.
PY - 1987/9
Y1 - 1987/9
N2 - Intercalates 3R{single bond}VS2NH3 and 3R{single bond}TaS2NH3, isostructural with 3R{single bond}TiS2NH3, are described for the first time. Magnetic properties of 3R{single bond}TiS2NH3, 3R{single bond}VS2NH3, and 2H{single bond}TaS2NH3 respectively are interpreted in terms of a charge transfer (in agreement with an ionic model) from the intercalant to the lowest conduction band which consists mainly ofeg, a1g anda′1 transition metald states.
AB - Intercalates 3R{single bond}VS2NH3 and 3R{single bond}TaS2NH3, isostructural with 3R{single bond}TiS2NH3, are described for the first time. Magnetic properties of 3R{single bond}TiS2NH3, 3R{single bond}VS2NH3, and 2H{single bond}TaS2NH3 respectively are interpreted in terms of a charge transfer (in agreement with an ionic model) from the intercalant to the lowest conduction band which consists mainly ofeg, a1g anda′1 transition metald states.
UR - http://www.scopus.com/inward/record.url?scp=0023417931&partnerID=8YFLogxK
U2 - 10.1016/0022-4596(87)90177-0
DO - 10.1016/0022-4596(87)90177-0
M3 - Article
AN - SCOPUS:0023417931
VL - 70
SP - 57
EP - 64
JO - Journal of solid state chemistry
JF - Journal of solid state chemistry
SN - 0022-4596
IS - 1
ER -