Magnetic properties of ammonia intercalates of some IV B and V B transition metal disulfides

H. J.M. Bouwmeester; G. A. Wiegers; C. F. van Bruggen

doi:10.1016/0022-4596(87)90177-0

Magnetic properties of ammonia intercalates of some IV B and V B transition metal disulfides

H. J.M. Bouwmeester, G. A. Wiegers^*, C. F. van Bruggen

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

1 Citation (Scopus)

Abstract

Intercalates 3R{single bond}VS₂NH₃ and 3R{single bond}TaS₂NH₃, isostructural with 3R{single bond}TiS₂NH₃, are described for the first time. Magnetic properties of 3R{single bond}TiS₂NH₃, 3R{single bond}VS₂NH₃, and 2H{single bond}TaS₂NH₃ respectively are interpreted in terms of a charge transfer (in agreement with an ionic model) from the intercalant to the lowest conduction band which consists mainly ofe_g, a_1g anda′₁ transition metald states.

Original language	English
Pages (from-to)	57-64
Number of pages	8
Journal	Journal of solid state chemistry
Volume	70
Issue number	1
DOIs	https://doi.org/10.1016/0022-4596(87)90177-0
Publication status	Published - Sep 1987
Externally published	Yes

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@article{2ea9d68f88354cf297f9b8c072feafbd,

title = "Magnetic properties of ammonia intercalates of some IV B and V B transition metal disulfides",

abstract = "Intercalates 3R{single bond}VS2NH3 and 3R{single bond}TaS2NH3, isostructural with 3R{single bond}TiS2NH3, are described for the first time. Magnetic properties of 3R{single bond}TiS2NH3, 3R{single bond}VS2NH3, and 2H{single bond}TaS2NH3 respectively are interpreted in terms of a charge transfer (in agreement with an ionic model) from the intercalant to the lowest conduction band which consists mainly ofeg, a1g anda′1 transition metald states.",

author = "Bouwmeester, {H. J.M.} and Wiegers, {G. A.} and {van Bruggen}, {C. F.}",

year = "1987",

month = sep,

doi = "10.1016/0022-4596(87)90177-0",

language = "English",

volume = "70",

pages = "57--64",

journal = "Journal of solid state chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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T1 - Magnetic properties of ammonia intercalates of some IV B and V B transition metal disulfides

AU - Bouwmeester, H. J.M.

AU - Wiegers, G. A.

AU - van Bruggen, C. F.

PY - 1987/9

Y1 - 1987/9

N2 - Intercalates 3R{single bond}VS2NH3 and 3R{single bond}TaS2NH3, isostructural with 3R{single bond}TiS2NH3, are described for the first time. Magnetic properties of 3R{single bond}TiS2NH3, 3R{single bond}VS2NH3, and 2H{single bond}TaS2NH3 respectively are interpreted in terms of a charge transfer (in agreement with an ionic model) from the intercalant to the lowest conduction band which consists mainly ofeg, a1g anda′1 transition metald states.

AB - Intercalates 3R{single bond}VS2NH3 and 3R{single bond}TaS2NH3, isostructural with 3R{single bond}TiS2NH3, are described for the first time. Magnetic properties of 3R{single bond}TiS2NH3, 3R{single bond}VS2NH3, and 2H{single bond}TaS2NH3 respectively are interpreted in terms of a charge transfer (in agreement with an ionic model) from the intercalant to the lowest conduction band which consists mainly ofeg, a1g anda′1 transition metald states.

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DO - 10.1016/0022-4596(87)90177-0

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JO - Journal of solid state chemistry

JF - Journal of solid state chemistry

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