Magnetic properties of ammonia intercalates of some IV B and V B transition metal disulfides

H. J.M. Bouwmeester, G. A. Wiegers*, C. F. van Bruggen

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

1 Citation (Scopus)

Abstract

Intercalates 3R{single bond}VS2NH3 and 3R{single bond}TaS2NH3, isostructural with 3R{single bond}TiS2NH3, are described for the first time. Magnetic properties of 3R{single bond}TiS2NH3, 3R{single bond}VS2NH3, and 2H{single bond}TaS2NH3 respectively are interpreted in terms of a charge transfer (in agreement with an ionic model) from the intercalant to the lowest conduction band which consists mainly ofeg, a1g anda′1 transition metald states.

Original languageEnglish
Pages (from-to)57-64
Number of pages8
JournalJournal of solid state chemistry
Volume70
Issue number1
DOIs
Publication statusPublished - Sep 1987
Externally publishedYes

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