Membrane distillation with porous metal hollow fibers for the concentration of thermo-sensitive solutions

Sushumna Shukla

Research output: ThesisPhD Thesis - Research external, graduation external

261 Downloads (Pure)

Abstract

This thesis presents an original approach for the concentration of thermo-sensitive solutions: the Sweep Gas Membrane Distillation (SGMD) process. A new membrane contactor with metallic hollow fibers has been designed and allows the distillation process to be operational at low temperature. Heat is generated in the fibers by the Joule effect, rather than being supplied as latent heat in the liquid bulk. The localized generation of heat results in a reduction of temperature polarization phenomena. The stainless-steel hollow fiber membranes have been synthetized with appropriate structural properties and sufficient mechanical strength. The pore surface of the fibers has been made hydrophobic by the deposition of a thin layer of an elastomer. Moreover, a novel and green method is presented to fabricate alumina and stainless-steel hollow fibers. This method is based on ionic gelation of a biopolymer and completely avoids the use of harmful solvents. By a detailed experimental study of the SGMD the influence of different operational parameters on the process performance has been investigated. The improvements in the flux and the separation efficiency using Joule effect have been successfully demonstrated, even in the case of pervaporation.
Original languageEnglish
Awarding Institution
  • KU Leuven
Supervisors/Advisors
  • Sanchez Marcano, Jose, Supervisor
  • Vankelecom, I.F.J., Co-Supervisor, External person
  • Benes, N.E., Co-Supervisor
Award date18 Dec 2014
Publisher
Publication statusPublished - 18 Dec 2014

Fingerprint

distillation
hollow
membranes
fibers
metals
stainless steels
contactors
heat
theses
biopolymers
latent heat
gelation
elastomers
gases
aluminum oxides
porosity
polarization
liquids
temperature

Keywords

  • METIS-310301
  • IR-101238

Cite this

Shukla, S. (2014). Membrane distillation with porous metal hollow fibers for the concentration of thermo-sensitive solutions. EUDIME: University of Montpellier 2, UT Universiteit Twente, Katholieke Universiteit Leuven.
Shukla, Sushumna. / Membrane distillation with porous metal hollow fibers for the concentration of thermo-sensitive solutions. EUDIME: University of Montpellier 2, UT Universiteit Twente, Katholieke Universiteit Leuven, 2014. 200 p.
@phdthesis{013d5fcd7bf84817b1ec9786ea0e359a,
title = "Membrane distillation with porous metal hollow fibers for the concentration of thermo-sensitive solutions",
abstract = "This thesis presents an original approach for the concentration of thermo-sensitive solutions: the Sweep Gas Membrane Distillation (SGMD) process. A new membrane contactor with metallic hollow fibers has been designed and allows the distillation process to be operational at low temperature. Heat is generated in the fibers by the Joule effect, rather than being supplied as latent heat in the liquid bulk. The localized generation of heat results in a reduction of temperature polarization phenomena. The stainless-steel hollow fiber membranes have been synthetized with appropriate structural properties and sufficient mechanical strength. The pore surface of the fibers has been made hydrophobic by the deposition of a thin layer of an elastomer. Moreover, a novel and green method is presented to fabricate alumina and stainless-steel hollow fibers. This method is based on ionic gelation of a biopolymer and completely avoids the use of harmful solvents. By a detailed experimental study of the SGMD the influence of different operational parameters on the process performance has been investigated. The improvements in the flux and the separation efficiency using Joule effect have been successfully demonstrated, even in the case of pervaporation.",
keywords = "METIS-310301, IR-101238",
author = "Sushumna Shukla",
note = "promotie i.h.k.v. EUDIME-project. Promotie aan 3 universiteiten: Montpellier, Leuven en Twente.",
year = "2014",
month = "12",
day = "18",
language = "English",
publisher = "EUDIME: University of Montpellier 2, UT Universiteit Twente, Katholieke Universiteit Leuven",
school = "KU Leuven",

}

Membrane distillation with porous metal hollow fibers for the concentration of thermo-sensitive solutions. / Shukla, Sushumna.

EUDIME: University of Montpellier 2, UT Universiteit Twente, Katholieke Universiteit Leuven, 2014. 200 p.

Research output: ThesisPhD Thesis - Research external, graduation external

TY - THES

T1 - Membrane distillation with porous metal hollow fibers for the concentration of thermo-sensitive solutions

AU - Shukla, Sushumna

N1 - promotie i.h.k.v. EUDIME-project. Promotie aan 3 universiteiten: Montpellier, Leuven en Twente.

PY - 2014/12/18

Y1 - 2014/12/18

N2 - This thesis presents an original approach for the concentration of thermo-sensitive solutions: the Sweep Gas Membrane Distillation (SGMD) process. A new membrane contactor with metallic hollow fibers has been designed and allows the distillation process to be operational at low temperature. Heat is generated in the fibers by the Joule effect, rather than being supplied as latent heat in the liquid bulk. The localized generation of heat results in a reduction of temperature polarization phenomena. The stainless-steel hollow fiber membranes have been synthetized with appropriate structural properties and sufficient mechanical strength. The pore surface of the fibers has been made hydrophobic by the deposition of a thin layer of an elastomer. Moreover, a novel and green method is presented to fabricate alumina and stainless-steel hollow fibers. This method is based on ionic gelation of a biopolymer and completely avoids the use of harmful solvents. By a detailed experimental study of the SGMD the influence of different operational parameters on the process performance has been investigated. The improvements in the flux and the separation efficiency using Joule effect have been successfully demonstrated, even in the case of pervaporation.

AB - This thesis presents an original approach for the concentration of thermo-sensitive solutions: the Sweep Gas Membrane Distillation (SGMD) process. A new membrane contactor with metallic hollow fibers has been designed and allows the distillation process to be operational at low temperature. Heat is generated in the fibers by the Joule effect, rather than being supplied as latent heat in the liquid bulk. The localized generation of heat results in a reduction of temperature polarization phenomena. The stainless-steel hollow fiber membranes have been synthetized with appropriate structural properties and sufficient mechanical strength. The pore surface of the fibers has been made hydrophobic by the deposition of a thin layer of an elastomer. Moreover, a novel and green method is presented to fabricate alumina and stainless-steel hollow fibers. This method is based on ionic gelation of a biopolymer and completely avoids the use of harmful solvents. By a detailed experimental study of the SGMD the influence of different operational parameters on the process performance has been investigated. The improvements in the flux and the separation efficiency using Joule effect have been successfully demonstrated, even in the case of pervaporation.

KW - METIS-310301

KW - IR-101238

M3 - PhD Thesis - Research external, graduation external

PB - EUDIME: University of Montpellier 2, UT Universiteit Twente, Katholieke Universiteit Leuven

ER -

Shukla S. Membrane distillation with porous metal hollow fibers for the concentration of thermo-sensitive solutions. EUDIME: University of Montpellier 2, UT Universiteit Twente, Katholieke Universiteit Leuven, 2014. 200 p.