Metallomacrocycles and -clefts: receptors for neutral molecules and anions

Dmitry M. Rudkevich; Wilhelm T.S. Huck; Frank C.J.M. van Veggel; David N. Reinhoudt

doi:10.1007/978-94-015-8380-0_18

Metallomacrocycles and -clefts: receptors for neutral molecules and anions

Dmitry M. Rudkevich, Wilhelm T.S. Huck, Frank C.J.M. van Veggel, David N. Reinhoudt

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic

Abstract

In this review the concept of immobilizing electrophilic centers in synthetic receptors is described. The design of neutral metallomacrocycles and metalloclefts with an immobilized electrophilic center (UO₂ ²⁺ etc.), combined with hydrogen bonding moieties, π-π-stacking, etc. proved to be a useful approach for complexation of polar neutral molecules and of anions. By systematic variation of the structures a high degree of specificity has been obtained.

The unique combination of binding sites for both cations and anions in a neutral receptor molecule leads to hosts with multifunctional complexation properties, eg. for the complexation of both constituents of a salts.

Original language	English
Title of host publication	Transition metals in supramolecular chemistry
Editors	Luigi Fabbrizzi, Antonio Poggi
Place of Publication	Dordrecht
Publisher	Kluwer Academic Publishers
Chapter	18
Pages	329-349
ISBN (Electronic)	978-94-015-8380-0
ISBN (Print)	978-90-481-4483-9
DOIs	https://doi.org/10.1007/978-94-015-8380-0_18
Publication status	Published - 1994
Event	NATO Advanced Research Workshop on Transition Metals in Supramolecular Chemistry 1994 - Santa Margherita Ligure, Genoa, Italy Duration: 14 Apr 1994 → 16 Apr 1994

Publication series

Name	NATO ASI Series C: Mathematical and Physical Sciences
Publisher	Kluwer Academic Publishers
Volume	448
ISSN (Print)	1389-2185

Workshop

Workshop	NATO Advanced Research Workshop on Transition Metals in Supramolecular Chemistry 1994
Country/Territory	Italy
City	Santa Margherita Ligure, Genoa
Period	14/04/94 → 16/04/94

Keywords

Association constant
Transition metal cation
Alkaline earth metal cation
Diisopropyl ether
Trinuclear complex

Access to Document

10.1007/978-94-015-8380-0_18

Cite this

Rudkevich, D. M., Huck, W. T. S., van Veggel, F. C. J. M., & Reinhoudt, D. N. (1994). Metallomacrocycles and -clefts: receptors for neutral molecules and anions. In L. Fabbrizzi, & A. Poggi (Eds.), Transition metals in supramolecular chemistry (pp. 329-349). (NATO ASI Series C: Mathematical and Physical Sciences; Vol. 448). Kluwer Academic Publishers. https://doi.org/10.1007/978-94-015-8380-0_18

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title = "Metallomacrocycles and -clefts: receptors for neutral molecules and anions",

abstract = "In this review the concept of immobilizing electrophilic centers in synthetic receptors is described. The design of neutral metallomacrocycles and metalloclefts with an immobilized electrophilic center (UO2 2+ etc.), combined with hydrogen bonding moieties, π-π-stacking, etc. proved to be a useful approach for complexation of polar neutral molecules and of anions. By systematic variation of the structures a high degree of specificity has been obtained.The unique combination of binding sites for both cations and anions in a neutral receptor molecule leads to hosts with multifunctional complexation properties, eg. for the complexation of both constituents of a salts.",

keywords = "Association constant, Transition metal cation, Alkaline earth metal cation, Diisopropyl ether, Trinuclear complex",

author = "Rudkevich, {Dmitry M.} and Huck, {Wilhelm T.S.} and {van Veggel}, {Frank C.J.M.} and Reinhoudt, {David N.}",

year = "1994",

doi = "10.1007/978-94-015-8380-0_18",

language = "English",

isbn = "978-90-481-4483-9",

series = "NATO ASI Series C: Mathematical and Physical Sciences",

publisher = "Kluwer Academic Publishers",

pages = "329--349",

editor = "Luigi Fabbrizzi and Antonio Poggi",

booktitle = "Transition metals in supramolecular chemistry",

address = "Netherlands",

note = "NATO Advanced Research Workshop on Transition Metals in Supramolecular Chemistry 1994 ; Conference date: 14-04-1994 Through 16-04-1994",

}

Rudkevich, DM, Huck, WTS, van Veggel, FCJM & Reinhoudt, DN 1994, Metallomacrocycles and -clefts: receptors for neutral molecules and anions. in L Fabbrizzi & A Poggi (eds), Transition metals in supramolecular chemistry. NATO ASI Series C: Mathematical and Physical Sciences, vol. 448, Kluwer Academic Publishers, Dordrecht, pp. 329-349, NATO Advanced Research Workshop on Transition Metals in Supramolecular Chemistry 1994, Santa Margherita Ligure, Genoa, Italy, 14/04/94. https://doi.org/10.1007/978-94-015-8380-0_18

Metallomacrocycles and -clefts: receptors for neutral molecules and anions. / Rudkevich, Dmitry M.; Huck, Wilhelm T.S.; van Veggel, Frank C.J.M. et al.
Transition metals in supramolecular chemistry. ed. / Luigi Fabbrizzi; Antonio Poggi. Dordrecht: Kluwer Academic Publishers, 1994. p. 329-349 (NATO ASI Series C: Mathematical and Physical Sciences; Vol. 448).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Academic

TY - CHAP

T1 - Metallomacrocycles and -clefts

T2 - NATO Advanced Research Workshop on Transition Metals in Supramolecular Chemistry 1994

AU - Rudkevich, Dmitry M.

AU - Huck, Wilhelm T.S.

AU - van Veggel, Frank C.J.M.

AU - Reinhoudt, David N.

PY - 1994

Y1 - 1994

N2 - In this review the concept of immobilizing electrophilic centers in synthetic receptors is described. The design of neutral metallomacrocycles and metalloclefts with an immobilized electrophilic center (UO2 2+ etc.), combined with hydrogen bonding moieties, π-π-stacking, etc. proved to be a useful approach for complexation of polar neutral molecules and of anions. By systematic variation of the structures a high degree of specificity has been obtained.The unique combination of binding sites for both cations and anions in a neutral receptor molecule leads to hosts with multifunctional complexation properties, eg. for the complexation of both constituents of a salts.

AB - In this review the concept of immobilizing electrophilic centers in synthetic receptors is described. The design of neutral metallomacrocycles and metalloclefts with an immobilized electrophilic center (UO2 2+ etc.), combined with hydrogen bonding moieties, π-π-stacking, etc. proved to be a useful approach for complexation of polar neutral molecules and of anions. By systematic variation of the structures a high degree of specificity has been obtained.The unique combination of binding sites for both cations and anions in a neutral receptor molecule leads to hosts with multifunctional complexation properties, eg. for the complexation of both constituents of a salts.

KW - Association constant

KW - Transition metal cation

KW - Alkaline earth metal cation

KW - Diisopropyl ether

KW - Trinuclear complex

U2 - 10.1007/978-94-015-8380-0_18

DO - 10.1007/978-94-015-8380-0_18

M3 - Chapter

SN - 978-90-481-4483-9

T3 - NATO ASI Series C: Mathematical and Physical Sciences

SP - 329

EP - 349

BT - Transition metals in supramolecular chemistry

A2 - Fabbrizzi, Luigi

A2 - Poggi, Antonio

PB - Kluwer Academic Publishers

CY - Dordrecht

Y2 - 14 April 1994 through 16 April 1994

ER -

Metallomacrocycles and -clefts: receptors for neutral molecules and anions

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