TY - JOUR
T1 - Methane conversion into synthetic fuels using microplasma reaction technology
AU - Agiral, Anil
AU - Nozaki, Tomohiro
AU - Nakase, Masahiko
AU - Yuzawa, Shuhei
AU - Goujard, Valentin
AU - Okazaki, Ken
AU - Gardeniers, J. G.E.
N1 - Conference code: 242
PY - 2011
Y1 - 2011
N2 - A direct and selective synthesis of oxygenates via methane partial oxidation at room temperature using a non-thermal discharge microreactor is described. Heat generated by methane partial oxidation was removed efficiently in the microreactor configuration. Low temperature synthesis promoted condensation of liquid components on the microreactor wall and pulsed water injection was introduced to wash out condensed oxygenates. In this contribution, the effect of pulsed water injection on methane conversion, the oxygenates yield, and the formation of hydrogen peroxide (H 2O 2) as an intermediate oxidation product are described. Results of the oxidizing effect of H 2O 2 on post-discharge liquid components are reported. The overall kinetics of the process is described by dividing into three different stages: electron impact dissoiation of reactants (oxygen and methane), successive radical reactions in the gas phase followed by condensation of oxygenates and self-oxidation in the post-discharge liquid.
AB - A direct and selective synthesis of oxygenates via methane partial oxidation at room temperature using a non-thermal discharge microreactor is described. Heat generated by methane partial oxidation was removed efficiently in the microreactor configuration. Low temperature synthesis promoted condensation of liquid components on the microreactor wall and pulsed water injection was introduced to wash out condensed oxygenates. In this contribution, the effect of pulsed water injection on methane conversion, the oxygenates yield, and the formation of hydrogen peroxide (H 2O 2) as an intermediate oxidation product are described. Results of the oxidizing effect of H 2O 2 on post-discharge liquid components are reported. The overall kinetics of the process is described by dividing into three different stages: electron impact dissoiation of reactants (oxygen and methane), successive radical reactions in the gas phase followed by condensation of oxygenates and self-oxidation in the post-discharge liquid.
UR - https://www.scopus.com/pages/publications/84861022040
M3 - Conference article
AN - SCOPUS:84861022040
SN - 0065-7727
JO - Abstracts of papers of the American Chemical Society
JF - Abstracts of papers of the American Chemical Society
T2 - 242nd ACS National Meeting and Exposition 2011
Y2 - 28 August 2011 through 1 September 2011
ER -