Mimicking the velcro system from nature for an alternative rubber/silica coupling system

Rafal Piotr Anyszka, Wilma K. Dierkes, Dariusz Bielinski, Essi Sarlin, Karolina Beton, Anke Blume

Research output: Contribution to conferencePoster

Abstract

Beside carbon black, silica becomes the most important filler for high-performance rubber products. However, unlike carbon black its surface properties are not favorable for providing satisfactory rubber/filler interactions. A significant amount of silanol groups present on the silica surface results in a considerably polar character, whereas most of rubbers exhibit a non-polar or relatively low-polar character. Because of this, various approaches towards different surface treatments of silica were made.

The aim of this research is to introduce an alternative type of rubber/silica coupling inspired by the velcro system existing in nature. The bio-mimicking mechanism is based on physical entanglements and steric hindrance between mutually soluble (based on calculated solubility parameters): cross-linked and entangled rubber macromolecules – acting as molecular loops - and oligomer brushes grafted onto the silica surface – acting as molecular hooks. This results in the formation of supramolecular hooks-and-loops, a rubber/silica interphase fastener exhibiting reconnectable performance.
Original languageEnglish
Publication statusPublished - 25 Mar 2019
EventDutch Polymer Days 2019 - Lunteren, Netherlands
Duration: 25 Mar 201926 Mar 2019
http://www.ptn.nu/symp/

Conference

ConferenceDutch Polymer Days 2019
Abbreviated titleDPD 2019
CountryNetherlands
CityLunteren
Period25/03/1926/03/19
Internet address

    Fingerprint

Cite this

Anyszka, R. P., Dierkes, W. K., Bielinski, D., Sarlin, E., Beton, K., & Blume, A. (2019). Mimicking the velcro system from nature for an alternative rubber/silica coupling system. Poster session presented at Dutch Polymer Days 2019, Lunteren, Netherlands.