Model polydiethylsiloxane networks: I. Synthesis and phase behaviour

G.J.J. Out; A.A. Turetski; M. Snijder; M. Möller; V.S. Papkov

doi:10.1016/0032-3861(95)97885-J

Model polydiethylsiloxane networks: I. Synthesis and phase behaviour

G.J.J. Out, A.A. Turetski, M. Snijder, M. Möller, V.S. Papkov

Materials Science and Technology of Polymers

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Abstract

The preparation and hydrosilylation crosslinking of well-defined vinyl and ally polydiethylsiloxane (PDES) telechelics are described. End functionalization has been achieved by using divinyltetramethylsiloxane as a chain stopper during the cationic polymerization of hexaethylcyclotrisiloxane or by anionic polymerization of hexaethylcyclotrisiloxane with allyllithium followed by end capping with allyldimethylchlorosilane. Hydrosilylation crosslinking yielded model PDES networks which have been characterized by equilibrium swelling, determination of the sol fraction, differential scanning calorimetry and wide angle X-ray diffraction.

Original language	English
Pages (from-to)	3213-3221
Journal	Polymer
Volume	36
Issue number	16
DOIs	https://doi.org/10.1016/0032-3861(95)97885-J
Publication status	Published - 1995

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title = "Model polydiethylsiloxane networks: I. Synthesis and phase behaviour",

abstract = "The preparation and hydrosilylation crosslinking of well-defined vinyl and ally polydiethylsiloxane (PDES) telechelics are described. End functionalization has been achieved by using divinyltetramethylsiloxane as a chain stopper during the cationic polymerization of hexaethylcyclotrisiloxane or by anionic polymerization of hexaethylcyclotrisiloxane with allyllithium followed by end capping with allyldimethylchlorosilane. Hydrosilylation crosslinking yielded model PDES networks which have been characterized by equilibrium swelling, determination of the sol fraction, differential scanning calorimetry and wide angle X-ray diffraction.",

author = "G.J.J. Out and A.A. Turetski and M. Snijder and M. M{\"o}ller and V.S. Papkov",

year = "1995",

doi = "10.1016/0032-3861(95)97885-J",

language = "English",

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pages = "3213--3221",

journal = "Polymer",

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TY - JOUR

T1 - Model polydiethylsiloxane networks

T2 - I. Synthesis and phase behaviour

AU - Out, G.J.J.

AU - Turetski, A.A.

AU - Snijder, M.

AU - Möller, M.

AU - Papkov, V.S.

PY - 1995

Y1 - 1995

N2 - The preparation and hydrosilylation crosslinking of well-defined vinyl and ally polydiethylsiloxane (PDES) telechelics are described. End functionalization has been achieved by using divinyltetramethylsiloxane as a chain stopper during the cationic polymerization of hexaethylcyclotrisiloxane or by anionic polymerization of hexaethylcyclotrisiloxane with allyllithium followed by end capping with allyldimethylchlorosilane. Hydrosilylation crosslinking yielded model PDES networks which have been characterized by equilibrium swelling, determination of the sol fraction, differential scanning calorimetry and wide angle X-ray diffraction.

AB - The preparation and hydrosilylation crosslinking of well-defined vinyl and ally polydiethylsiloxane (PDES) telechelics are described. End functionalization has been achieved by using divinyltetramethylsiloxane as a chain stopper during the cationic polymerization of hexaethylcyclotrisiloxane or by anionic polymerization of hexaethylcyclotrisiloxane with allyllithium followed by end capping with allyldimethylchlorosilane. Hydrosilylation crosslinking yielded model PDES networks which have been characterized by equilibrium swelling, determination of the sol fraction, differential scanning calorimetry and wide angle X-ray diffraction.

U2 - 10.1016/0032-3861(95)97885-J

DO - 10.1016/0032-3861(95)97885-J

M3 - Article

SN - 0032-3861

VL - 36

SP - 3213

EP - 3221

JO - Polymer

JF - Polymer

IS - 16

ER -

Model polydiethylsiloxane networks: I. Synthesis and phase behaviour

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