Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

G.I. Spijksma, Henricus J.M. Bouwmeester, David H.A. Blank, Vadim G. Kessler

Research output: Contribution to journalArticleAcademicpeer-review

19 Citations (Scopus)

Abstract

New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.
Original languageUndefined
Pages (from-to)953-955
Number of pages3
JournalInorganic chemistry communications
Volume7
Issue number8
DOIs
Publication statusPublished - 2004

Keywords

  • Heterometallic alkoxides
  • METIS-222016
  • Nona-coordinated zirconium
  • X-ray structure
  • IR-49506

Cite this

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title = "Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics",
abstract = "New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.",
keywords = "Heterometallic alkoxides, METIS-222016, Nona-coordinated zirconium, X-ray structure, IR-49506",
author = "G.I. Spijksma and Bouwmeester, {Henricus J.M.} and Blank, {David H.A.} and Kessler, {Vadim G.}",
year = "2004",
doi = "10.1016/j.inoche.2004.06.006",
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volume = "7",
pages = "953--955",
journal = "Inorganic chemistry communications",
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publisher = "Elsevier",
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Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics. / Spijksma, G.I.; Bouwmeester, Henricus J.M.; Blank, David H.A.; Kessler, Vadim G.

In: Inorganic chemistry communications, Vol. 7, No. 8, 2004, p. 953-955.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

AU - Spijksma, G.I.

AU - Bouwmeester, Henricus J.M.

AU - Blank, David H.A.

AU - Kessler, Vadim G.

PY - 2004

Y1 - 2004

N2 - New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.

AB - New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.

KW - Heterometallic alkoxides

KW - METIS-222016

KW - Nona-coordinated zirconium

KW - X-ray structure

KW - IR-49506

U2 - 10.1016/j.inoche.2004.06.006

DO - 10.1016/j.inoche.2004.06.006

M3 - Article

VL - 7

SP - 953

EP - 955

JO - Inorganic chemistry communications

JF - Inorganic chemistry communications

SN - 1387-7003

IS - 8

ER -