Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

G.I. Spijksma, Henricus J.M. Bouwmeester, David H.A. Blank, Vadim G. Kessler

Research output: Contribution to journalArticleAcademicpeer-review

19 Citations (Scopus)

Abstract

New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.
Original languageUndefined
Pages (from-to)953-955
Number of pages3
JournalInorganic chemistry communications
Volume7
Issue number8
DOIs
Publication statusPublished - 2004

Keywords

  • Heterometallic alkoxides
  • METIS-222016
  • Nona-coordinated zirconium
  • X-ray structure
  • IR-49506

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