Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

G.I. Spijksma; Henricus J.M. Bouwmeester; David H.A. Blank; Vadim G. Kessler

doi:10.1016/j.inoche.2004.06.006

Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

G.I. Spijksma
, Henricus J.M. Bouwmeester
, David H.A. Blank
, Vadim G. Kessler

Research output: Contribution to journal › Article › Academic › peer-review

22 Citations (Scopus)

3 Downloads (Pure)

Abstract

New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.

Original language	Undefined
Pages (from-to)	953-955
Number of pages	3
Journal	Inorganic chemistry communications
Volume	7
Issue number	8
DOIs	https://doi.org/10.1016/j.inoche.2004.06.006
Publication status	Published - 2004

Keywords

Heterometallic alkoxides
METIS-222016
Nona-coordinated zirconium
X-ray structure
IR-49506

Access to Document

10.1016/j.inoche.2004.06.006

Cite this

@article{05164580fdcc439d8cc1fa9adc9067ce,

title = "Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics",

abstract = "New heterometallic interesting trinuclear, Zr\{η3, μ2-NH(C2H4O)2\}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.",

keywords = "Heterometallic alkoxides, METIS-222016, Nona-coordinated zirconium, X-ray structure, IR-49506",

author = "G.I. Spijksma and Bouwmeester, \{Henricus J.M.\} and Blank, \{David H.A.\} and Kessler, \{Vadim G.\}",

year = "2004",

doi = "10.1016/j.inoche.2004.06.006",

language = "Undefined",

volume = "7",

pages = "953--955",

journal = "Inorganic chemistry communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "8",

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TY - JOUR

T1 - Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

AU - Spijksma, G.I.

AU - Bouwmeester, Henricus J.M.

AU - Blank, David H.A.

AU - Kessler, Vadim G.

PY - 2004

Y1 - 2004

N2 - New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.

AB - New heterometallic interesting trinuclear, Zr{η3, μ2-NH(C2H4O)2}3[Ti(OiPr)3]2 encountering a nona-coordinated central zirconium atom crystallizes at −30 °C from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L=1:2:3) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol–gel technique for the preparation of mixed metal oxide materials.

KW - Heterometallic alkoxides

KW - METIS-222016

KW - Nona-coordinated zirconium

KW - X-ray structure

KW - IR-49506

U2 - 10.1016/j.inoche.2004.06.006

DO - 10.1016/j.inoche.2004.06.006

M3 - Article

SN - 1387-7003

VL - 7

SP - 953

EP - 955

JO - Inorganic chemistry communications

JF - Inorganic chemistry communications

IS - 8

ER -