Molecular dynamics and energy landscape of decanethiolates in self-assembled monolayers on Au(111) by STM

Kai Sotthewes, Hairong Wu, Avijit Kumar, Gyula J. Vancso, Peter Manfred Schön, Henricus J.W. Zandvliet

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

The energetics and dynamics of the various phases of decanethiolate self-assembled monolayers on Au(111) surfaces were studied with scanning tunneling microscopy. We have observed five different phases of the decanethiolate monolayer on Au(111): four ordered phases (β, δ, χ*, and ) and one disordered phase (ε). We have determined the boundary free energies between the disordered and order phases by analyzing the thermally induced meandering of the domain boundaries. On the basis of these results, we are able to accurately predict the two-dimensional phase diagram of the decanethiolate/Au(111) system. The order–disorder phase transition of the χ* phase occurs at 295 K, followed by the order–disorder phase transition of the β phase at 325 K. Above temperatures of 325 K, only the densely packed and disordered ε phases remain. Our findings are in good agreement with the phase diagram of the decanethiolate/Au(111) system that was put forward by Poirier et al
Original languageEnglish
Pages (from-to)3662-3667
Number of pages6
JournalLangmuir
Volume29
Issue number11
DOIs
Publication statusPublished - 2013

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Self assembled monolayers
Phase diagrams
Molecular dynamics
Phase transitions
phase diagrams
molecular dynamics
Scanning tunneling microscopy
Free energy
scanning tunneling microscopy
Monolayers
free energy
energy
Temperature
temperature

Cite this

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title = "Molecular dynamics and energy landscape of decanethiolates in self-assembled monolayers on Au(111) by STM",
abstract = "The energetics and dynamics of the various phases of decanethiolate self-assembled monolayers on Au(111) surfaces were studied with scanning tunneling microscopy. We have observed five different phases of the decanethiolate monolayer on Au(111): four ordered phases (β, δ, χ*, and ) and one disordered phase (ε). We have determined the boundary free energies between the disordered and order phases by analyzing the thermally induced meandering of the domain boundaries. On the basis of these results, we are able to accurately predict the two-dimensional phase diagram of the decanethiolate/Au(111) system. The order–disorder phase transition of the χ* phase occurs at 295 K, followed by the order–disorder phase transition of the β phase at 325 K. Above temperatures of 325 K, only the densely packed and disordered ε phases remain. Our findings are in good agreement with the phase diagram of the decanethiolate/Au(111) system that was put forward by Poirier et al",
author = "Kai Sotthewes and Hairong Wu and Avijit Kumar and Vancso, {Gyula J.} and Sch{\"o}n, {Peter Manfred} and Zandvliet, {Henricus J.W.}",
year = "2013",
doi = "10.1021/la400082z",
language = "English",
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pages = "3662--3667",
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Molecular dynamics and energy landscape of decanethiolates in self-assembled monolayers on Au(111) by STM. / Sotthewes, Kai; Wu, Hairong; Kumar, Avijit; Vancso, Gyula J.; Schön, Peter Manfred; Zandvliet, Henricus J.W.

In: Langmuir, Vol. 29, No. 11, 2013, p. 3662-3667.

Research output: Contribution to journalArticleAcademicpeer-review

TY - JOUR

T1 - Molecular dynamics and energy landscape of decanethiolates in self-assembled monolayers on Au(111) by STM

AU - Sotthewes, Kai

AU - Wu, Hairong

AU - Kumar, Avijit

AU - Vancso, Gyula J.

AU - Schön, Peter Manfred

AU - Zandvliet, Henricus J.W.

PY - 2013

Y1 - 2013

N2 - The energetics and dynamics of the various phases of decanethiolate self-assembled monolayers on Au(111) surfaces were studied with scanning tunneling microscopy. We have observed five different phases of the decanethiolate monolayer on Au(111): four ordered phases (β, δ, χ*, and ) and one disordered phase (ε). We have determined the boundary free energies between the disordered and order phases by analyzing the thermally induced meandering of the domain boundaries. On the basis of these results, we are able to accurately predict the two-dimensional phase diagram of the decanethiolate/Au(111) system. The order–disorder phase transition of the χ* phase occurs at 295 K, followed by the order–disorder phase transition of the β phase at 325 K. Above temperatures of 325 K, only the densely packed and disordered ε phases remain. Our findings are in good agreement with the phase diagram of the decanethiolate/Au(111) system that was put forward by Poirier et al

AB - The energetics and dynamics of the various phases of decanethiolate self-assembled monolayers on Au(111) surfaces were studied with scanning tunneling microscopy. We have observed five different phases of the decanethiolate monolayer on Au(111): four ordered phases (β, δ, χ*, and ) and one disordered phase (ε). We have determined the boundary free energies between the disordered and order phases by analyzing the thermally induced meandering of the domain boundaries. On the basis of these results, we are able to accurately predict the two-dimensional phase diagram of the decanethiolate/Au(111) system. The order–disorder phase transition of the χ* phase occurs at 295 K, followed by the order–disorder phase transition of the β phase at 325 K. Above temperatures of 325 K, only the densely packed and disordered ε phases remain. Our findings are in good agreement with the phase diagram of the decanethiolate/Au(111) system that was put forward by Poirier et al

U2 - 10.1021/la400082z

DO - 10.1021/la400082z

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SP - 3662

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JO - Langmuir

JF - Langmuir

SN - 0743-7463

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