Molecular materials from 1,3,2-dithiazolyls. Solid-state structuresand magnetic properties of 2,3-naphthalene and quinoxalinederivatives

Tosha M. Barclay; A. Wallace Cordes; Noel A. George; R. C. Haddon; Richard T. Oakley; Thom T.M.  Palstra; Gregory W. Patenaude; Robert W. Reed; John F. Richardson; Hongzhou Zhang

doi:10.1039/A700310B

Molecular materials from 1,3,2-dithiazolyls. Solid-state structuresand magnetic properties of 2,3-naphthalene and quinoxalinederivatives

Tosha M. Barclay, A. Wallace Cordes, Noel A. George, R. C. Haddon, Richard T. Oakley, Thom T.M. Palstra, Gregory W. Patenaude, Robert W. Reed, John F. Richardson, Hongzhou Zhang

University of Twente

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Abstract

In the solid state, at room temperature, the radicals 2,3-naphthalene-1,3,2-dithiazolyl (NDTA) and quinoxaline-1,3,2-dithiazolyl (QDTA) are not dimerized; discrete molecules of NDTA are packed in a herringbone fashion, while those of QDTA adopt a slipped π-stack motif; NDTA is essentially paramagnetic at ambient temperatures, with weak antiferromagnetism developing below 190 K; QDTA is diamagnetic at low temperature, but limited paramagnetism sets in above 120 K.

Original language	English
Pages (from-to)	873-874
Journal	Chemical communications
Volume	1997
Issue number	9
DOIs	https://doi.org/10.1039/A700310B
Publication status	Published - 1997

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Barclay, T. M., Cordes, A. W., George, N. A., Haddon, R. C., Oakley, R. T., Palstra, T. T. M., Patenaude, G. W., Reed, R. W., Richardson, J. F., & Zhang, H. (1997). Molecular materials from 1,3,2-dithiazolyls. Solid-state structuresand magnetic properties of 2,3-naphthalene and quinoxalinederivatives. Chemical communications, 1997(9), 873-874. https://doi.org/10.1039/A700310B

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title = "Molecular materials from 1,3,2-dithiazolyls. Solid-state structuresand magnetic properties of 2,3-naphthalene and quinoxalinederivatives",

abstract = "In the solid state, at room temperature, the radicals 2,3-naphthalene-1,3,2-dithiazolyl (NDTA) and quinoxaline-1,3,2-dithiazolyl (QDTA) are not dimerized; discrete molecules of NDTA are packed in a herringbone fashion, while those of QDTA adopt a slipped π-stack motif; NDTA is essentially paramagnetic at ambient temperatures, with weak antiferromagnetism developing below 190 K; QDTA is diamagnetic at low temperature, but limited paramagnetism sets in above 120 K.",

author = "Barclay, {Tosha M.} and Cordes, {A. Wallace} and George, {Noel A.} and Haddon, {R. C.} and Oakley, {Richard T.} and Palstra, {Thom T.M.} and Patenaude, {Gregory W.} and Reed, {Robert W.} and Richardson, {John F.} and Hongzhou Zhang",

year = "1997",

doi = "10.1039/A700310B",

language = "English",

volume = "1997",

pages = "873--874",

journal = "Chemical communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Molecular materials from 1,3,2-dithiazolyls. Solid-state structuresand magnetic properties of 2,3-naphthalene and quinoxalinederivatives

AU - Barclay, Tosha M.

AU - Cordes, A. Wallace

AU - George, Noel A.

AU - Haddon, R. C.

AU - Oakley, Richard T.

AU - Palstra, Thom T.M.

AU - Patenaude, Gregory W.

AU - Reed, Robert W.

AU - Richardson, John F.

AU - Zhang, Hongzhou

PY - 1997

Y1 - 1997

N2 - In the solid state, at room temperature, the radicals 2,3-naphthalene-1,3,2-dithiazolyl (NDTA) and quinoxaline-1,3,2-dithiazolyl (QDTA) are not dimerized; discrete molecules of NDTA are packed in a herringbone fashion, while those of QDTA adopt a slipped π-stack motif; NDTA is essentially paramagnetic at ambient temperatures, with weak antiferromagnetism developing below 190 K; QDTA is diamagnetic at low temperature, but limited paramagnetism sets in above 120 K.

AB - In the solid state, at room temperature, the radicals 2,3-naphthalene-1,3,2-dithiazolyl (NDTA) and quinoxaline-1,3,2-dithiazolyl (QDTA) are not dimerized; discrete molecules of NDTA are packed in a herringbone fashion, while those of QDTA adopt a slipped π-stack motif; NDTA is essentially paramagnetic at ambient temperatures, with weak antiferromagnetism developing below 190 K; QDTA is diamagnetic at low temperature, but limited paramagnetism sets in above 120 K.

U2 - 10.1039/A700310B

DO - 10.1039/A700310B

M3 - Article

SN - 1359-7345

VL - 1997

SP - 873

EP - 874

JO - Chemical communications

JF - Chemical communications

IS - 9

ER -

Molecular materials from 1,3,2-dithiazolyls. Solid-state structuresand magnetic properties of 2,3-naphthalene and quinoxalinederivatives

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