Molecular recognition by artificial receptors

Willem Verboom; Dmitry M. Rudkevich; David N. Reinhoudt

doi:10.1351/pac199466040679

Molecular recognition by artificial receptors

Willem Verboom, Dmitry M. Rudkevich, David N. Reinhoudt

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Abstract

Biological and synthetic receptors for three different types of guest species have been compared: valinomycin and calix[4]crown ethers for K⁺, urease and metallomacrocycles for urea, and phosphate binding proteins and synthetic anion receptors for different anions. The symbiosis of synthetic and biological receptors is demonstrated for transesterification reactions of amino acid esters by a-chymotrypsin in organic solvents in the presence of crown ethers.

Original language	English
Pages (from-to)	679-686
Journal	Pure and applied chemistry
Volume	66
Issue number	4
DOIs	https://doi.org/10.1351/pac199466040679
Publication status	Published - 1994

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title = "Molecular recognition by artificial receptors",

abstract = "Biological and synthetic receptors for three different types of guest species have been compared: valinomycin and calix[4]crown ethers for K+, urease and metallomacrocycles for urea, and phosphate binding proteins and synthetic anion receptors for different anions. The symbiosis of synthetic and biological receptors is demonstrated for transesterification reactions of amino acid esters by a-chymotrypsin in organic solvents in the presence of crown ethers.",

author = "Willem Verboom and Rudkevich, {Dmitry M.} and Reinhoudt, {David N.}",

year = "1994",

doi = "10.1351/pac199466040679",

language = "English",

volume = "66",

pages = "679--686",

journal = "Pure and applied chemistry",

issn = "0033-4545",

publisher = "IUPAC Secretariat",

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TY - JOUR

T1 - Molecular recognition by artificial receptors

AU - Verboom, Willem

AU - Rudkevich, Dmitry M.

AU - Reinhoudt, David N.

PY - 1994

Y1 - 1994

N2 - Biological and synthetic receptors for three different types of guest species have been compared: valinomycin and calix[4]crown ethers for K+, urease and metallomacrocycles for urea, and phosphate binding proteins and synthetic anion receptors for different anions. The symbiosis of synthetic and biological receptors is demonstrated for transesterification reactions of amino acid esters by a-chymotrypsin in organic solvents in the presence of crown ethers.

AB - Biological and synthetic receptors for three different types of guest species have been compared: valinomycin and calix[4]crown ethers for K+, urease and metallomacrocycles for urea, and phosphate binding proteins and synthetic anion receptors for different anions. The symbiosis of synthetic and biological receptors is demonstrated for transesterification reactions of amino acid esters by a-chymotrypsin in organic solvents in the presence of crown ethers.

U2 - 10.1351/pac199466040679

DO - 10.1351/pac199466040679

M3 - Article

SN - 0033-4545

VL - 66

SP - 679

EP - 686

JO - Pure and applied chemistry

JF - Pure and applied chemistry

IS - 4

ER -

Molecular recognition by artificial receptors

Abstract

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